2-Diphenylphosphinoyl-acetyl as a Remote Directing Group for the Highly Stereoselective Synthesis ofβ-Glycosides  

作　　者：Xianglai Liu Yetong Lin Ao Liu Qianhui Sun Huiyong Sun Peng Xu Guolong Li Yingying Song Weijia Xie Haopeng Sun Biao Yu Wei Li 

机构地区：[1]Department of Medicinal Chemistry,School of Pharmacy,China Pharmaceutical University,639 Longmian Avenue,Nanjing,Jiangsu 211198,China [2]State Key Laboratory of Bioorganic and Natural Products Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,345 Lingling Road,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2022年第4期443-452,共10页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.21977115 and 21672248).

摘　　要：Comprehensive Summary The configuration of the anomeric glycosidic linkages is crucial for maintaining the biological functions and activities of carbohydrate molecules.However,their stereochemistry control in glycosylation represents one of the most challenging tasks in carbohydrate chemistry.

关 键 词：GLYCOSYLATION DIASTEREOSELECTIVITY Hydrogen bonds 2-Diphenylphosphinoyl-acetyl 2-Deoxy sugars 

分 类 号：O62[理学—有机化学]