气相色谱质谱法检测食品有机磷农药残留的效果研究  

Determination of Organophosphorus Pesticide Residues in Food by Gas Chromatography-Mass Spectrometry

作　　者：孙翠玉 王跃武 曹虎 SUN Cuiyu;WANG Yuewu;CAO Hu(Zibo City Zhoucun District Inspection and Testing Center,Zibo 255300,China;Zoucheng Inspection and Testing Center,Zoucheng 273500,China;Yantai City Haiyang Inspection and Testing Center,Haiyang 265100,China)

机构地区：[1]淄博市周村区检验检测中心,山东淄博255300 [2]邹城市检验检测中心,山东邹城273500 [3]烟台市海阳市检验检测中心,山东海阳265100

出　　处：《食品安全导刊》2023年第3期95-97,共3页China Food Safety Magazine

摘　　要：目的:探讨气相色谱-质谱法(Gas Chromatography-Mass Spectrometry,GC-MS)检测食品有机磷农药残留的效果。方法:使用GS-MS法检测有机磷农药残留,对比不同提取剂的提取效率,不同提取方式的净化效果。结果:15 min时农药残留提取率高于12~14 min(P<0.05);提取剂中乙腈提取率最高(P<0.05);QuEChERs与Carb/NH2两种提取法的提取率无显著差异(P>0.05)。结论:GS-MS法能有效提取常见有机磷农药残留,提取剂种类中乙腈提取有效性较高,而提取方式可根据实际条件灵活选用。Objective:To explore the effect of gas chromatography-mass spectrometry(GC-MS)on the detection of organophosphorus pesticide residues in food.Method:GS-MS method was used to detect organophosphorus pesticide residues,and the extraction efficiency of different extractants and the purification effect of different extraction methods were investigated.Result:The extraction rate of pesticide residues at 15 min was higher than that at 12~14 min(P<0.05).The extraction rate of acetonitrile was the highest(P<0.05).There was no significant difference between QuEChERs and Carb/NH2 extraction methods(P>0.05).Conclusion:GS-MS method can effectively extract organophosphorus pesticide residues.Among the extractants,acetonitrile extraction is more effective,and the extraction method can be flexibly selected according to the actual conditions.

关 键 词：食品检测 有机磷农药残留 气相色谱-质谱法 

分 类 号：O657.63[理学—分析化学] TS207.53[理学—化学]