Electrochemical borylation of nitroarenes  

作　　者：Linlin Du Binfeng Zhang Shuohan Ji Hu Cai Hua Zhang 

机构地区：[1]Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials Science,School of Chemistry and Materials Science,South-Central Minzu University,Wuhan,430074,China [2]School of Chemistry and Chemical Engineering,Nanchang University,Nanchang,330031,China

出　　处：《Science China Chemistry》2023年第2期534-539,共6页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(21602096)。

摘　　要：A simple electrochemically mediated method for the conversion of nitroarenes to aryl boronic esters is presented.Electrochemical borylation of a diverse range of nitroarenes,including the late-stage borylation of bioactive molecules,is furnished at room temperature under simple conditions,thereby demonstrating the broad utility and functional-group tolerance of this protocol.This transformation provides a convenient and practical access to aryl boronic esters from widely available nitroarenes,which would significantly streamline the synthetic process of diverse functionalized arenes.

关 键 词：ELECTROCHEMISTRY BORYLATION NITROARENES arylboronic esters organic synthesis 

分 类 号：O62[理学—有机化学]