Coordination-assisted, transition-metal-catalyzed enantioselective desymmetric C–H functionalization  

作　　者：Xin Yu Zhuo-Zhuo Zhang Jun-Long Niu Bing-Feng Shi 

机构地区：[1]Department of Chemistry,Zhejiang University,Hangzhou,Zhejiang,310027,China [2]School of Food and Biological Engineering,Chengdu University,Chengdu,Sichuan,610106,China [3]Green Catalysis Center,College of Chemistry,Zhengzhou University,Zhengzhou 450001,China

出　　处：《Organic Chemistry Frontiers》2022年第5期1458-1484,共27页有机化学前沿（英文）

基　　金：Financial support from the NSFC(21925109,21772170,21801223,and 21772179);the China Postdoctoral Science Foundation(No.2020M671689);the Center of Chemistry for Frontier Technologies of Zhejiang University is gratefully acknowledged.

摘　　要：Transition-metal-catalyzed asymmetric C–H functionalization has gradually emerged as a powerful tool for the creation of structural and chiral complexity in an atom-and step-economical fashion.The nature of this strategy provides a variety of methodologies to overcome the limitation of enantioselective desym-metrization caused by the synthesis of preformed multifunctional symmetric substrates.

关 键 词：CATALYZED SYMMETRIC ENANTIOSELECTIVE 

分 类 号：O62[理学—有机化学]