AgF-Mediated Dialkylation of Activate Alkenes: An Efficient Access to Nitrile-Containing Spirooxindoles  

作　　者：Liang Wu Pinhong Chen Guosheng Liu 

机构地区：[1]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2014年第8期681-684,共4页中国化学（英文版）

基　　金：We are grateful for financial support from 973 Program(No.2011CB808700);NSFC(Nos.21225210,20923005 and 21121062);STCSM(No.11JC1415000);the CAS/SAFEA International Partnership Program for Creative Research Teams.

摘　　要：A novel Ag-mediated dialkylation reaction of alkenes was disclosed,in which AgF was essential to activate C-H bond of acetonitrile.This reaction provided an efficient way to nitrile-containing spirooxindoles from readily available(1H-indol-3-yl)methanamine derivatives.

关 键 词：SPIROOXINDOLES activated alkenes silver fluoride ACETONITRILE C-H bond cleavage 

分 类 号：O62[理学—有机化学]