Sustainable electrochemical dearomatization for the synthesis of diverse 2,3-functionalized indolines  

作　　者：Jun Chen Rong Zhang Caiyan Ma Peng Zhang Yonghong Zhang Bin Wang Fei Xue Weiwei Jin Yu Xia Chenjiang Liu 

机构地区：[1]Urumqi Key Laboratory of Green Catalysis and Synthesis Technology,Key Laboratory of Oil and Gas Fine Chemicals,Ministry of Education&Xinjiang Uygur Autonomous Region,State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources,College of Chemistry,College of Future Technology,Xinjiang University,Urumqi 830017,China

出　　处：《Green Synthesis and Catalysis》2024年第1期25-30,共6页绿色合成与催化（英文）

基　　金：We are grateful to the National Natural Science Foundation of China(Nos.21961037,21861036,22161044 and 22201241);the Program for Tianshan Innovative Research Team of Xinjiang Uygur Autonomous Region(No.2021D14011);the Natural Science Foundation of Xinjiang Uygur Autonomous Region(Nos.2020D01C077 and 2021D01E10);the Key Program of Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2022D01D06)for support of this research。

摘　　要：Herein,we achieved a green and efficient dearomatization for the synthesis of 2,3-functionalized polycyclic indolines in an electrochemical way.This avoiding of external oxidants and metals approach allowed various nucleophilic sources(Nu¼anilines,TMSN3 and ROH)to perform the products,representing an environmentally benign means.Additionally,the continuous flow electrosynthesis and synthetic transformations also reveal the strong practicality of electrochemistry in organic synthesis.

关 键 词：Green synthesis Organic electrochemistry INDOLE DEAROMATIZATION CYCLIZATION 

分 类 号：O62[理学—有机化学]