Controlling hydrogenation of C=C and C=O bonds in cinnamaldehyde using Pt_(1)/Ni and Pt_(1)/Co single-atom alloy catalysts  

作　　者：Huan-Shi Lan Yi-Da Yang Qing-Di Sun Hao Zhang Ying Zhang Qian He Ran Chen Guo-Yi Bai Xiao-Hui He Hong-Bing Ji 

机构地区：[1]School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China [2]Key Laboratory of Bioinorganicand Synthetic Chemistry of Ministry of Education,Fine Chemical Industry Research Institute,School of Chemistry,IGCME,Sun Yat-sen University,Guangzhou510275,China [3]UBFC,CNRS,ENSMM,FEMTO-ST Institute,25030 Besancon CEDEX,France [4]College of Chemistry and Materials Science,Hebei University,Baoding 071002,China [5]State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology,Institute of Green Petroleum Processing and Light Hydrocarbon Conversion,College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,China

出　　处：《Rare Metals》2024年第6期2859-2868,共10页稀有金属（英文版）

基　　金：financially supported by the National key Research and Development Program Nanotechnology Specific Project(No.2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(No.2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(No.2022B1515020035);Guangdong Provincial Key R&D Programme(No.2019B110206002);the National Natural Science Foundation of China(Nos.22078371,21938001 and 21961160741);Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT0IC102);the NSF of Guangdong Province(No.2020A1515011141);the Science and Technology Project of Guangzhou City,China(No.202102020461);Special funding for"Guangxi Bagui Scholars"。

摘　　要：Selective hydrogenation of C=C and C=O bonds in cinnamaldehyde(CAL)to produce desired products is a challenging task due to the complex conjugate system of the two unsaturated functional groups.In this study,a simple ball milling method is presented for synthesizing Pt-based single-atom alloy catalysts(SAAs)that can function as a control switch for the selective hydrogenation of CAL into highly valuable products.

关 键 词：alloy HYDROGENATION CONJUGATE 

分 类 号：TQ426[化学工程]