Energy Valorization by Continuous Pyrolysis of Straight Vegetable Oils (SVOs)  

作　　者：Abollé Abollé Konan Edmond Kouassi Henri Planche Albert Trokourey Kouassi Benjamin Yao Ado Ado Gossan 

机构地区：[1]Unité de Formation et de Recherche-SFA, Université Nangui Abrogoua (UNA), Abidjan, Republic of Cô te d’Ivoire [2]Unité de Chimie et Procédés, Ecole Nationale Supérieure des Techniques Avancées, Paris, France [3]Unité de Formation et de Recherche-SSMT, Université Houphouë t-Boigny (UFHB), Abidjan, Republic of Cô te d’Ivoire [4]Institut National Polytechnique Félix Houphouë t-Boigny, Yamoussoukro, Republic of Cô te d’Ivoire

出　　处：《Green and Sustainable Chemistry》2018年第1期19-31,共13页绿色与可持续化学（英文）

摘　　要：Researches have been undertaken to find a form of valorization of the surplus production of vegetable oils in C&#244te d’Ivoire for their use as a substitute diesel. The first tests of the use of crude oils-diesel blends by the company Palmindustrie faced enormous difficulties. We have therefore undertaken a campaign of pyrolysis of Tropical Straight Vegetable Oils: palm, copra, peanut, cotton, cabbage palm and shea, between 400°C and 600°C under atmospheric pressure. A silica support was used in co-catalysis either with water or with methylcyclohexane, which is a model compound of cetanes contained in gas oil. This compound has the advantage, unlike the gas oil itself, of not masking the peaks of the pyrolysis recombinates of oils in the chromatograms. The condensed organic phase consists mainly of hydrocarbons including paraffins, olefins, alkylbenzenes and styrenes. The yields of liquid hydrocarbons vary between 72% and 86%. A comparative study of coke precursors and gas production was carried out. A discussion on the parameters to be considered for a large-scale implementation was undertaken.Researches have been undertaken to find a form of valorization of the surplus production of vegetable oils in C&#244te d’Ivoire for their use as a substitute diesel. The first tests of the use of crude oils-diesel blends by the company Palmindustrie faced enormous difficulties. We have therefore undertaken a campaign of pyrolysis of Tropical Straight Vegetable Oils: palm, copra, peanut, cotton, cabbage palm and shea, between 400°C and 600°C under atmospheric pressure. A silica support was used in co-catalysis either with water or with methylcyclohexane, which is a model compound of cetanes contained in gas oil. This compound has the advantage, unlike the gas oil itself, of not masking the peaks of the pyrolysis recombinates of oils in the chromatograms. The condensed organic phase consists mainly of hydrocarbons including paraffins, olefins, alkylbenzenes and styrenes. The yields of liquid hydrocarbons vary between 72% and 86%. A comparative study of coke precursors and gas production was carried out. A discussion on the parameters to be considered for a large-scale implementation was undertaken.

关 键 词：Straight VEGETABLE OILS (Palm Copra PEANUT PALM Kernel Cotton and Shea) Hydrocarbons COKE 

分 类 号：O6[理学—化学]