Project supported by the National Natural Science Foundation of China (Grant Nos. 29706104 and 29573112);the State Key Laboratory of Theoretical and Computational Chemistry of Jilin University.
After the separation of the donor, the acceptor, and the σ-type bridge from the π-σ-π system, the geometries of biphenyl, biphenyl anion radical, naphthalene, and naphthalene anion radical are optimized, and then ...