国家自然科学基金(20525101)

作品数:9被引量:10H指数:2
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相关作者:张勇陈阳曹向前陈金香李红喜更多>>
相关机构:苏州大学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《化学学报》更多>>
相关主题:CRYSTAL_STRUCTURESYNTHESISDCABISDICYANAMIDE更多>>
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Syntheses and Crystal Structures of Two Heterobimetallic Clusters [WOS_3Cu_3I(dmpzm)_2]·2(MeCN)_(0.5) and [WS_4Cu_4I_2(dmpzm)_2]·DMF(dmpzm=Bis(3,5-dimethylpyrazolyl)methane)
《Chinese Journal of Structural Chemistry》2010年第6期861-868,共8页任玉树 陈阳 李端秀 郭承鑫 乔善宝 李红喜 任志刚 郎建平 
Supported by the National Natural Science Foundation of China (No. 20525101,20801038); "Soochow Scholar" Program of Suzhou University
The reaction of [Et4N]2WOS3 with three equiv.of CuI and dmpzm in MeCN afforded [WOS3Cu3I(dmpzm)2]·2(MeCN)0.5(1·2(MeCN)0.5) while that of [PPh4]2WS4 with four equiv.of CuI in DMF/MeCN followed by the addition...
关键词:tungsten cluster copper(I) cluster sulfur cluster bis(3 5-dimethylpyrazolyl)methane) synthesis crystal structure 
Synthesis and Crystal Structure of a New Mo/Au/S Cluster [Et_4N][Mo_2S_4(AuPPh_3)(edt)_2]· 0.25Et_2O·0.25MeOH(edt=Ethanedithiolate)
《Chinese Journal of Structural Chemistry》2009年第6期669-672,共4页张文华 虞虹 唐晓艳 张勇 郎建平 
supported by the National Natural Science Foundation of China (No. 20525101 and 20871088);the "SooChow Scholar" Program and Program for Innovative Research Team of Suzhou University
Reactions of the preformed cluster precursor [Et4N]2[Mo2S2(μ-S)2(edt)2] (edt = ethanedithiolate) (1) with [Au(PPh3)Cl] in MeOH/MeCN gave rise to a new heterobimetallic Mo/Au/S cluster [Et4N][Mo2S4(AuPPh3)...
关键词:molybdenum duster gold(I) duster sulfur cluster synthesis crystal structure 
Synthesis,Crystal Structure and Luminescent Properties of [Ag(bzdmpymt)]_6·2MeOH(bzdmpymtH = 5-Benzyl-4,6-dimethylpyrimidine-2-thione)被引量:1
《Chinese Journal of Structural Chemistry》2009年第5期631-635,共5页崔玉微 李红喜 唐晓艳 陈阳 郎建平 
supported by the National Natural Science Foundation of China (No. 20525101, 20801038);the NSF of the Education Committee of Jiangsu Province (No. 07KJD150182); "Soochow Scholar" Program of Suzhou University
Reaction of AgAc with bzdmpymtH in MeOH resulted in the title compound [Ag(bzdmpymt)]6-2MeOH (1.2MeOH), which was structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis...
关键词:Ag(I) complex SYNTHESIS crystal structure luminescent property 
Synthesis and Crystal Structure of [Cu_3(dmpzm)_4(μ-1,3-dca)_2(dca)_4]·2H_2O (dmpzm=1,1'-Methylenebis-(3,5-dimethyl-1H-pyrazole),dca=dicyanamide)
《Chinese Journal of Structural Chemistry》2008年第5期588-592,共5页王春兰 陈阳 张勇 郎建平 
The project was supported by the National Natural Science Foundation of China (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);State Key Laboratory of Coordination Chemistry
The title compound, [Cu3(dmpzm)4(μ-1,3-dca)2(dca)4]·2H2O (dmpzm = 1,1'-methylenebis(3,5-dimethyl-lH-pyrazole), dca = dicyanamide) 1·2H2O, was synthesized via the reaction of CuCl2·2H2O with dmpzm and Na...
关键词:copper(Ⅱ) complex 1 1'-methylenebis(3 5-dimethyl-1H-pyrazole) DICYANAMIDE synthesis crystal structure 
Synthesis,Structure and Luminescent Properties of [Zn(btzb)_2Cl_2]·2H_2O [btzb=1,2-Bis(5-tetrazolyl)benzene]
《Chinese Journal of Structural Chemistry》2008年第3期335-339,共5页刘东 陈阳 李红喜 任志刚 张勇 郎建平 
the National Natural Science Foundation of China (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);State Key Laboratory of Coordination Chemistry
The title compound [Zn(btzb)2Cl2]·2H2O (1·2H2O, btzb = 1,2-bis(5-tetrazolyl)ben- zene) was synthesized in situ by the [2+3] cycloaddition reaction of phthalonitrile with NaN3 in water in the presence of ZnCl2...
关键词:zinc(II) complex 1 2-bis(5-tetrazolyl)benzene SYNTHESIS crystal structure luminescent properties 
Synthesis and Crystal Structure of an Incomplete Cubane-like Heterobimetallic Cluster [(η^5-C5Me5)2Mo2(μ3-S)(μ-S)3(CuCl)]
《Chinese Journal of Structural Chemistry》2007年第4期427-430,共4页黎玲玲 任志刚 郎建平 
The project was supported by the NNSFC (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);the State Key Laboratory of Organometallic Chemistry (No. 06-26)
The reaction of[(η^5-C5Me5)2Mo2(μ3-S)(μ-S)3(CuCl)]1 with Na2S in MeCN produced a trinuclear cluster [(η^5-C5Me5)2Mo2(μ3-S)(μ-S)3(CuCl)] 2. 2 crystallizes in the monoclinic system, space group P21...
关键词:SYNTHESIS crystal structure molybdenum cluster copper cluster 
Construction of a Novel 2D Polymer [Co(dmpzm)(dca)2]∞ from Reaction of a Mononuclear Complex [Co(dmpzm)Cl2] with Sodium Dicyanamide (dca) [dmpzm=bis(3,5-dimethylpyrazolyl)methane]被引量:7
《Chinese Journal of Chemistry》2006年第12期1716-1720,共5页李巧云 张文华 李红喜 唐晓燕 郎建平 张勇 王新益 高松 
Project supported by the 0utstanding Young Scientist Award from the National Natural Science Foundation of China (No. 20525101), the Natural Science Foundation of Jiangsu Province (No. BK2004205), and the Research Funds (No. 20050285004) for the Doctoral Program of Higher Educa- tion of China.
Reaction of COC12.6H20 with equimolar bis(3,5-dimethylpyrazolyl)methane (dmpzm) produced a mononuclear adduct [Co(dmpzm)Cl2] (1). Treatment of 1 with sodium dicyanamide (dca) afforded a polymeric complex [Co...
关键词:COBALT coordination polymer synthesis crystal structure magnetic property 
三维多孔配位聚合物{[Zn_2(mal)_2(4,4'-bipy)(H_2O)_2]·2(H_2O)_(0.25)}_∞(mal=丙二酸根)的合成、结构及性质研究被引量:2
《化学学报》2006年第24期2496-2500,共5页曹向前 陈金香 陈阳 李红喜 任志刚 张勇 郎建平 
国家自然科学基金(No.20525101);江苏省自然科学研究基金(No.KB2004205);中国科学院上海有机化学研究所金属有机化学国家重点实验室(No.06-26)资助项目.
ZnO,丙二酸及4,4'-bipy按物质的量之比1∶3∶0.3溶于H2O和DMF混合溶剂中(体积比4∶1),形成的无色溶液在50℃反应3d,得到了标题化合物{[Zn2(mal)2(4,4'-bipy)(H2O)2]?2(H2O)0.25}∞(mal=丙二酸根),对其进行了元素分析、红外光谱和X射线...
关键词:锌配合物 丙二酸根 4 4’-联吡啶 晶体结构 合成 聚合物 
Synthesis and Crystal Structure of a Copper(II) Complex with a Tab-Tab Disulfide Ligand (Tab-Tab)[CuBr_4](Tab=Trimethylammoniumphenyl-4-thiolate)
《Chinese Journal of Structural Chemistry》2006年第9期1100-1104,共5页TANG Xiao-Yan CHEN Jin-Xiang LANG Jian-Ping 
The project was supported by the National Natural Science Foundation of China (No. 20525101), the NSF of Jiangsu Province (No. BK2004205), State Key Laboratory of Structural Chemistry (No. 030066) and Key Laboratory of Organic Synthesis of Jiangsu Province (No. JSK001)
Reaction of CuBr2 with TabHPF6/Et3N in methanol followed by dissolving the resulting precipitate in hydrobromic acid yielded purple blocks of the title complex [Tab-Tab][CuBr4] 1 (C18H26CuBraN2S2). 1 crystallizes in...
关键词:tetrabromocuprate(Ⅱ) DISULPHIDE synthesis crystal structure 
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