Supported by the National Natural Science Foundation of China (No. 20525101,20801038); "Soochow Scholar" Program of Suzhou University
The reaction of [Et4N]2WOS3 with three equiv.of CuI and dmpzm in MeCN afforded [WOS3Cu3I(dmpzm)2]·2(MeCN)0.5(1·2(MeCN)0.5) while that of [PPh4]2WS4 with four equiv.of CuI in DMF/MeCN followed by the addition...
supported by the National Natural Science Foundation of China (No. 20525101 and 20871088);the "SooChow Scholar" Program and Program for Innovative Research Team of Suzhou University
Reactions of the preformed cluster precursor [Et4N]2[Mo2S2(μ-S)2(edt)2] (edt = ethanedithiolate) (1) with [Au(PPh3)Cl] in MeOH/MeCN gave rise to a new heterobimetallic Mo/Au/S cluster [Et4N][Mo2S4(AuPPh3)...
supported by the National Natural Science Foundation of China (No. 20525101, 20801038);the NSF of the Education Committee of Jiangsu Province (No. 07KJD150182); "Soochow Scholar" Program of Suzhou University
Reaction of AgAc with bzdmpymtH in MeOH resulted in the title compound [Ag(bzdmpymt)]6-2MeOH (1.2MeOH), which was structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis...
The project was supported by the National Natural Science Foundation of China (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);State Key Laboratory of Coordination Chemistry
The title compound, [Cu3(dmpzm)4(μ-1,3-dca)2(dca)4]·2H2O (dmpzm = 1,1'-methylenebis(3,5-dimethyl-lH-pyrazole), dca = dicyanamide) 1·2H2O, was synthesized via the reaction of CuCl2·2H2O with dmpzm and Na...
the National Natural Science Foundation of China (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);State Key Laboratory of Coordination Chemistry
The title compound [Zn(btzb)2Cl2]·2H2O (1·2H2O, btzb = 1,2-bis(5-tetrazolyl)ben- zene) was synthesized in situ by the [2+3] cycloaddition reaction of phthalonitrile with NaN3 in water in the presence of ZnCl2...
The project was supported by the NNSFC (No. 20525101);the NSF of Jiangsu Province (No. BK2004205);the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20050285004);the State Key Laboratory of Organometallic Chemistry (No. 06-26)
The reaction of[(η^5-C5Me5)2Mo2(μ3-S)(μ-S)3(CuCl)]1 with Na2S in MeCN produced a trinuclear cluster [(η^5-C5Me5)2Mo2(μ3-S)(μ-S)3(CuCl)] 2. 2 crystallizes in the monoclinic system, space group P21...
Project supported by the 0utstanding Young Scientist Award from the National Natural Science Foundation of China (No. 20525101), the Natural Science Foundation of Jiangsu Province (No. BK2004205), and the Research Funds (No. 20050285004) for the Doctoral Program of Higher Educa- tion of China.
Reaction of COC12.6H20 with equimolar bis(3,5-dimethylpyrazolyl)methane (dmpzm) produced a mononuclear adduct [Co(dmpzm)Cl2] (1). Treatment of 1 with sodium dicyanamide (dca) afforded a polymeric complex [Co...
The project was supported by the National Natural Science Foundation of China (No. 20525101), the NSF of Jiangsu Province (No. BK2004205), State Key Laboratory of Structural Chemistry (No. 030066) and Key Laboratory of Organic Synthesis of Jiangsu Province (No. JSK001)
Reaction of CuBr2 with TabHPF6/Et3N in methanol followed by dissolving the resulting precipitate in hydrobromic acid yielded purple blocks of the title complex [Tab-Tab][CuBr4] 1 (C18H26CuBraN2S2). 1 crystallizes in...