国家自然科学基金(U1162114)

作品数：4被引量：16H指数：2
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Boron- and silicon-bridged bis(diphenylphosphino)-type ligands for chromium-catalyzed ethylene oligomerization被引量：2
《Chinese Science Bulletin》2014年第21期2613-2617,共5页Yueming Sun Yanhui Chen Guoliang Mao Yingnan Ning Tao Jiang 
supported by the National Natural Science Foundation of China (U1162114,U1362110);the Program for New Century Excellent Talents in University (NCET-070142)
PNP-type ligands showed very good property in the catalytic systems of PNP/Cr(Ⅲ)/methylaluminoxane(MAO)for ethylene selective tetramerization toward1-octene.In this research,two PNP analogues bis(diphenylphosphino)ph...
关键词：二苯基膦 催化体系 乙烯 低聚 配体 硅桥连 PNP型 铬 
Preparation of Spherical MgCl_2/SiO_2/THF-Supported Late-Transition Metal Catalysts for Ethylene Polymerization
《China Petroleum Processing & Petrochemical Technology》2014年第3期77-83,共7页Bai Wei Gao Xianglu Wu Haotian Cao Chengang Jiang Tao 
supported by the National Natural Science Foundation of China (Grant No.U1162114);the Science Foundation of Tianjin University of Science & Technology (20090420)
A facile and user friendly technique to immobilize the late-transition metal complexes on spherical MgCl2/SiO2/THF support has been developed. The spherical MgCl2/SiO2/THF-supported late-transition metal catalysts 2,6...
关键词：MgCl2/SiO2/THF support late-transition metal catalyst polymerization of ethylene SPRAY-DRYING 
Preparation and Catalytic Performance of Silica-Supported Cr(acac)_3/PNP for Ethylene Tetramerization被引量：1
《China Petroleum Processing & Petrochemical Technology》2014年第1期45-51,共7页Shao Huaiqi Li Yafei Gao Xianglu Zhang Baojun Yi Jianjun Jiang Tao Li Jian 
supported by the National Natural Science Foundation of China (U1162114);the PetroChina Innovation Foundation (2012D-5006-0501);the Tianjin Municipal Education Commission of China (20110505);the Natural Science Foundation of Tianjin (12JCQNJC06000);the Program for New Century Excellent Talents in University (NCET-07-0142)
Chromium acetylacetonate and bis(diphenylphosphino)isopropylamine were coordinated in situ and supported on methylaluminoxane-modified silica. The catalyst structure and effects of reaction temperature, reaction press...
关键词：ethylene tetramerization 1-OCTENE Cr(acac)3/PNP supported catalyst 
Ethylene tetramerization with a highly active and long-lifetime trinuclear diphenylphosphinoamine/Cr(III)/MAO catalyst被引量：13
《Chinese Science Bulletin》2012年第13期1510-1515,共6页JIANG Tao TAO YiQing GAO XiangLu MAO GuoLiang CHEN HongXia CAO ChenGang NING YingNan 
supported by the National Natural Science Foundation of China (U1162114);the Program for New Century Excellent Talents in University;the Program for New Century Excellent Talents in Heilongjiang Provincial University(NCET-06-010);the Science Foundation of Tianjin University of Science & Technology (20090420)
The synthesis and characterization of a novel trinuclear diphosphinoamine ligand 2 are reported. The ligand combined with Cr(III), activated with methylaluminoxane, lead to highly active and long-lifetime catalytic sy...
关键词：乙烯产生 铬(Ⅲ) 助催化剂 长寿命 高活性 三核 甲基铝氧烷 双膦配体 
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