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国家自然科学基金(90206040): 作品数：11被引量：15H指数：2; 导出分析报告; 相关作者：杨文斌卢灿忠吴小园何翔张全争更多>>; 相关机构：中国科学院福建物质结构研究所中国科学院研究生院更多>>; 相关期刊：《无机化学学报》《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》更多>>; 相关主题：HYDROTHERMAL_SYNTHESISCRYSTAL_STRUCTURECUPHENIN_SITU更多>>; 相关领域：理学更多>>

Conformation Diversity of Complexes Constructed by N-(2-Pyridylmethyl)-phenylalanine and Zn(Ⅱ)被引量：1: 《Chinese Journal of Structural Chemistry》2009年第1期53-60,共8页李新发刘庆燕谢在来李涛海李亚峰曹荣; Supported by 973 Program (2006CB932900);NNSFC (90206040, 20325106, 20521101);NSF of Fujian Province (2005HZ01-1, E0520003, 2005J058, 2006F3134);"The Distinguished Oversea Scholar Project" and "One Hundred Talent Project" from CAS; Four configurationally and conformationally related Zn（II） complexes with a tridentate ligand namely, N-（2-pyridylmethyl）-phenylalanine （Hpmpa）, have been synthesized by hydrothermal reactions. [Zn（L-α-pmpa）2...; 关键词：zinc Complex amino acid CONFORMATION configuration ISOMERISM

Hydrothermal Synthesis, Crystal Structure and Magnetic Property of a Novel Mixed Valence Decatungstate: [Cu(2,2′-bipy)_2]_2Na_2W_6~VW4^(VI)O_(30)·2H_2O被引量：1: 《Chinese Journal of Structural Chemistry》2008年第1期57-62,共6页李涛海吕健高水英曹荣; Supported by the NNSFC (90206040);NSF of Fujian Province (2006F3134, 2005J058); A novel Cu（II）-2,2＇-bipy-supported （bipy = bipyridine） mixed valence decatungstate, [Cu（2,2＇-bipy）2]2Na2W6^VW4^VIO30·2H2O 1, has been synthesized and structurally characterized by X-ray analysis. The crystal ...; 关键词：crystal structure DECATUNGSTATE mixed valence magnetic property

A Novel Hybrid Solid Constructed from Tetramolybdate and Copper Complexes with Mixed Ligands: [{(Cu·phen)_2(tp)}{(Cu·phen·H_2O)_2(tp)}{Mo_4O_(14)}]被引量：1: 《Chinese Journal of Structural Chemistry》2007年第4期389-394,共6页吴小园翟全国陈丽娟杨文斌卢灿忠; This work was supported by the 973 program of the MOST (001CB108906);the National Natural Science Foundation of China (20425313, 90206040, 20333070, 20303021);the Natural Science Foundation of Fujian Province (2005HZ01-1)and the Chinese Academy of Sciences; A novel copper molybdate with mixed ligands, [{（Cu·phen）e（tp）} {（Cu·phen·H2O）2（tp）} {Mo4O14}（phen = 1,10-phcnanthroline, tp = tercphthalate） 1, has been hydrothermally synthesized and structurally charact...; 关键词：POLYOXOMETALATE I 10-phenanthroline terephthalate tetramolybdate cluster crystal structure

Synthesis,Structure and Luminescence of a Novel 2D Cadmium Coordination Polymer with a Ligand Generated in situ: 《Chinese Journal of Structural Chemistry》2007年第3期333-337,共5页HUANG Xi-He SHENG Tian-Lu XIANG Sheng-Chang FU Rui-Biao HU Sheng-Min LI Ya-Min WU Xin-Tao; the State Key Laboratory of Structural Chemistry, the 973 program (2006CB932900);the NNSFC (20673118, 20333070, 90206040 and 90406024);NSF of Fujian Province (2006J0014, 2004HZ01-1, and 2005HZ01-1); The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd（NO3）2 affords a novel 2D cadmium tetrazolyl-benzoate, {Cd（tzbz）（H2O）}n （H2tzbz is 2-（5-tetrazolyl）-benzoate）. The tzbz ligand i...; 关键词：hydrothermal synthesis in situ crystal structure CADMIUM

Synthesis and Structure of a Dinuclear Copper(Ⅱ)-ditetrazolate Involving in situ Ligand Synthesis: 《Chinese Journal of Structural Chemistry》2007年第2期161-164,共4页HUANG Xi-He SHENG Tian-Lu XIANG Sheng-Chang FU Rui-Biao HU Sheng-Min LI Ya-Min WU Xin-Tao; This work was supported by the State Key Laboratory of Structural Chemistry, the National Ministry of Science and Technology of China (001CB1089);the NNSFC (20333070, 90206040 and 90406024) ;NSF of Fujian Province (2004J041, 2004HZ01-1, and 2005HZ01-1); The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of CuC12, 2,2＇-bipyridine and H2O affords a novel dinuclear copper（Ⅱ）-ditetrazolate, [Cu（bpy）- （pdtz）]2 （Hpdtz = 5,5＂-1,2-phenylene-d...; 关键词：hydrothermal synthesis in situ crystal structure COPPER ditetrazolate

由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H_3O)_3{[Na_3(H_2O)_(13)][(Cu(Gly)_2)_2(H_2W_(12)O_(42))]}·11H_2O(英文)被引量：2: 《无机化学学报》2006年第8期1511-1516,共6页吴小园张全争何翔陈淑妹杨文斌卢灿忠; 973项目(No.001CB108906);国家自然科学基金资助项目(No.20425313,90206040,20333070,20303021,20521101);福建省自然科学基金资助项目(No.2005HZ01-1); A new compound, (H3O)3{Na3(H2O)13(Cu(Gly)2)2(H2W12O42)}·11H2O (1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid...; 关键词：有机无机杂化材料水热合成晶体结构钨多酸氨基酸

两个由1,1′-环己烷二乙酸构筑的镉的配合物的合成、晶体结构和荧光性质(英文)被引量：7: 《无机化学学报》2006年第8期1380-1386,共7页何锦润王玉玲毕文华曹荣; 国家自然科学基金(No.90206040,20325106,20333070);福建省自然科学基金(No.E0520003);中科院'百人计划'项目基金资助; 通过邻羧苯乙酸、1,10-邻菲啰啉及硝酸镉的溶剂热反应合成了2个配合物:[Cd(phen)(chdc)]n(1)和[Cd(phen)(chdc)(H2O)]n(2)。X-射线单晶衍射显示:1是梯状双链结构;2是单链结构,单链再通过氢键连接成双链。虽然1和2的组分相似,但它们在固...; 关键词：柔性配体镉配合物 1 1′一环己烷二乙酸溶剂热合成荧光

2-羟基萘甲醛苯甲酰腙作配体的钼和钒两个化合物的合成和晶体结构(英文)被引量：3: 《无机化学学报》2006年第6期1028-1032,共5页刘九辉吴小园张全争何翔杨文斌卢灿忠; 国家自然科学基金资助项目(No.90206040,20333070,20303021);973资助项目(001CB108906);福建省自然科学基金资助(No.2005HZ01-1)。; 2-羟基萘甲醛苯甲酰腙(H2L)由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得。利用H2L分别合成了钼和钒的配合物,[MoO2(EtOH)L](1)和[VO(OMe)L(MeOH)](2),并测定了它们的晶体结构。配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位...; 关键词：2-羟基萘甲醛苯甲酰腙钼和钒合成和结构

The Effects of Metal Ions and Secondary Ligands on the Formation of Structures Resulted from Flexible Building Blocks: 《Chinese Journal of Structural Chemistry》2005年第12期1462-1467,共6页LI Feng LI Tao-Hai CAO Rong; This work was supported by the National Nature Science Foundation of China (90206040, 20325106, 20333070); Two coordination polymers have been synthesized from cpg/4,4＇-bipy/metal ions reaction system, [Zn（cpg）（4,4＇-bipy）0.5（H2O）]·H2O 1 and [Cd（cpg）（4,4＇-bipy）0.5（H2O）2]·H2O 2. X- ray analyses show that dif...; 关键词：hydrothermal synthesis flexible ligand prediction

Synthesis,Structure and Characterization of Bis(ethylene-1,2-dithiolate)(μ_(2)-di-2-pyridyl-ketone p-phenyldiamine-N,N')-tin(IV)Dichloromethane: 《Chinese Journal of Structural Chemistry》2005年第12期1355-1358,共4页WANG Long-Sheng ZHANG Jian-Jun HU Sheng-Min FU Rui-Biao WU Xin-Tao; supported by the State Key Laboratory of Structural Chemistry,the NNSFC(20273073,20333070,90206040);NSF of Fujian Province(2004J041,2003J042,2004HZ01-1); A new mononuclear tin（Ⅳ） complex [Sn（edt）2L]·CH2Cl2 （edt = ethane-1,2-dithiolate, L = di-2-pyridyl-ketone p-phenyldiamine） was obtained by a one-pot reaction which involves in situ formation of a new Schiff-ba...; 关键词：TIN p-phenyldiamine ethene-1 2-thiolate di-2-pyridyl-ketone Schiff-base

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