国家自然科学基金(91122028)

作品数：12被引量：6H指数：1
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相关机构：北京理工大学福建农林大学中国科学院福建物质结构研究所更多>>
相关期刊：《Science China Chemistry》《Chinese Journal of Structural Chemistry》《Chemical Research in Chinese Universities》《计算机与应用化学》更多>>
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A new 28-Ni-added poly(polyoxometalate)with B atoms:synthesis,structure and catalysis for Knoevenagel condensation被引量：1
《Science China Chemistry》2023年第5期1394-1399,共6页Chen Lian Hai-Lou Li Guo-Yu Yang 
supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young scholars(20725101)。
The synergistic effect of trivacant B-α-Ge W_(9)O_(34)fragments as structure-directing agents and inorganic B-O segments as intramolecular decoration afforded an unprecedented 28-Ni-added huge cluster K_(2)Na_(14)H_(...
关键词：POLYOXOMETALATE hydrothermal synthesis high-nuclearity TMAPs knoevenagel condensation 
Two New Borates Built by Different Types of{B_(9)}Cluster Units被引量：1
《Chemical Research in Chinese Universities》2022年第3期744-749,共6页CHEN Juan WANG Jiajia CHEN Chongan YANG Guoyu 
This work was supported by the National Natural Science Foundation of China(Nos.21831001,21571016,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new belt-like borates Na_(4)[B_(9)O_(14)(OH)_(3)]·0.5H_(2)O(1)and Na_(5)[B_(9)O_(14)(OH)_(4)](2)have been synthesized under solvothermal conditions.Both compounds contain unprecedented B_(9)O_(16)(OH)_(n)^((n+5))...
关键词：Oxoboron cluster SYNTHESIS BORATE Supramolecular framework Structure 
A ring-shaped 12-Ti-substituted poly(polyoxometalate):synthesis,structure,and catalytic properties被引量：1
《Science China Chemistry》2022年第5期892-897,共6页Hai-Lou Li Chen Lian Guo-Yu Yang 
supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young Scholars(20725101)。
A new ring-shaped 12-Ti-substituted poly(polyoxometalate)(poly(POM)),K_(10)H_(15)[{K_(2)Na(H_(2)O)_(3)}@{(Ti_(2)O)_(2)(Ti_(4)O_(4))_(2)(A-α-1,3,5-GeW_(9)O_(36))_(2)(A-α-2,3,4-GeW_(9)O_(36))_(2)}]·45H_(2)O(1),has be...
关键词：POLYOXOMETALATE hydrothermal synthesis Ti-oxo cluster chiral catalytic oxidation 
An unprecedented dumbbell-shaped pentadeca-nuclear W-Er heterometal cluster stabilizing nanoscale hexameric arsenotungstate aggregate and electrochemical sensing properties of its conductive hybrid film-modified electrode被引量：1
《Nano Research》2022年第4期3628-3637,共10页Dan Wang Jun Jiang Meng-Ya Cao Sai-Sai Xie Ya-Min Li Li-Juan Chen Jun-Wei Zhao Guo-Yu Yang 
This work was supported by the National Natural Science Foundation of China(Nos.21871077,21671054,21771052,22071042,22171070,91122028,and 21831001);the Program for Innovation Teams in Science and Technology in Universities of Henan Province(No.20IRTSTHN004).
Cluster-based functional materials have made remarkable progress owing to their wonderful structures and distinctive physicochemical performances,one of on-going advancements of which is basically driven by synthetic ...
关键词：POLYOXOMETALATE lanthanide-inserted arsenotungstate polyoxometalate-based conductive film 
A New Tubular Borate Built by[B_(14)O_(24)(OH)_(6)]^(12-) Cluster Units被引量：1
《Chemical Research in Chinese Universities》2022年第1期123-127,共5页SUN Xiao-Shuang QIN Dan LI Xu-Yan YANG Guo-Yu 
This work was supported by the National Natural Science Foundation of China (Nos.21571016,21831001,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Anew mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis...
关键词：Alkali and alkaline-earth metal BORATE Tube Solvothermal synthesis CLUSTER 
两种基于B_(5)O_(n)(n=11,12)簇构筑的具有深紫外吸收的硼酸盐被引量：2
《高等学校化学学报》2022年第1期197-202,共6页陈崇安 杨国昱 
国家自然科学基金(批准号:21831001,21571016,91122028);国家杰出青年科学基金(批准号:20725101)资助~~。
以碱金属和碱土金属为模板,在溶剂热条件下合成了两种具有深紫外吸收特性的硼酸盐Na_(2)Ba·[B_(5)O_(8)(OH)]_(2)·2H_(2)O(1)和KSr[B_(5)O_(8)(OH)_(2)](2),并利用单晶X射线衍射(SCXRD)、粉末X射线衍射(PXRD)、傅里叶变换红外(FTIR)...
关键词：硼氧团簇 溶剂热合成 层状结构 短边吸收 
诱导聚集与协同配位策略构筑金属氧合团簇及其有机骨架
《中国科学：化学》2020年第9期975-985,共11页方伟慧 杨国昱 
国家自然科学基金(编号:21771181,21831001,21571016,91122028,20725101);中国科学院青年创新促进会(编号:2017345)资助项目。
随着金属有机骨架(metal organic frameworks,MOFs)和金属氧合团簇(metal oxo clusters,MOCs)两大领域的不断发展壮大,形成了一种新的材料—金属簇有机骨架(metal cluster organic frameworks,MCOFs).由于这种材料同时结合了金属氧合团...
关键词：氧合团簇 金属簇有机骨架 诱导聚集 协同配位 
Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D{B5}/{B6}Helical Chains
《Chemical Research in Chinese Universities》2020年第1期86-90,共5页QIU Qiming SUN Kening YANG Guoyu 
Supported by the National Natural Science Foundation of China(Nos.21571016,21831001 and 91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new alkaline metal borates containing 1D{B5}/{B6}oxoboron helical chains,namely Na0.5[B5O8(OH)2]0.5[B5O6(OH)2]0.5·0.5H3O(1)and NaKCs[B6O9(OH)3](2)were synthesized under solvothermal conditions.Compound 1 contains...
关键词：Alkaline metal borate Solvothermal synthesis Helical chain Supramolecular framework 
A New 3-D Supramolecular Framework Built by Co4-Substituted Sandwiched Phosphotungstates, Organoamines and Co-Complexes: Synthesis, Structure, and Property被引量：1
《Chinese Journal of Structural Chemistry》2019年第9期1585-1592,共8页MA Wei-Dan LI Hai-Lou YANG Guo-Yu 
supported by the NSFC(Nos.21571016,21831001 and 91122028);the NSFC for Distinguished Young Scholars(No.20725101)
A neoteric organic-inorganic hybrid Co-substituted phosphotungstate H6{[Co(en)2(OAc)2]2[Co4(H2 O)2(PW9 O34)2]}?2 H2 en?36 H2 O(1, en = enthylenediamine) has been made under hydrothermal conditions and characterized by...
关键词：POLYOXOMETALATE HYDROTHERMAL SYNTHESIS 3-D SUPRAMOLECULAR framework adsorption properties 
Synthesis and DFT Calculation of a Four- coordinated Manganese Compound Mn_2(BPTC)
《Chinese Journal of Structural Chemistry》2015年第8期1170-1178,共9页RONG Cheng LIU Jin-Ying LIN Jian-Di LI Qing-Lu 
supported by the Natural Science Foundation of Fujian Province(No.2014J01029);the National Natural Science Foundation of China(No.91122028)
A new four-coordinated manganese compound Mn2（BPTC） （BPTC =- biphenyl- 2,4,4＇,6-tetracarboxylate） with flu topology net was synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis con...
关键词：four-coordinated manganese compound steric hindrance METAL-ORGANIC 
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