国家自然科学基金(91122031)

作品数:8被引量:6H指数:2
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相关作者:芦昌盛陈琪王冬妮丁刘镠徐杨更多>>
相关机构:南京工业大学南京大学大连理工大学更多>>
相关期刊:《无机化学学报》《Chinese Journal of Structural Chemistry》《Science China Chemistry》《中国科学:化学》更多>>
相关主题:MAGNETIZATIONCRYSTAL_STRUCTURECYANIDE-BRIDGEDBIMETALLICMAGNET更多>>
相关领域:理学更多>>
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Coexistence of metamagnetism and single chain magnet behavior in a Fe^Ⅲ_2Co^Ⅱ layer compound
《Science China Chemistry》2016年第6期735-739,共5页Wenjing Jiang Yanjuan Zhang Chengqi Jiao Liang Zhao Jixiang Hu Junli Wang Tao Liu 
supported by the National Natural Science Foundation of China (21201028, 21421005, 21322103, 91422302, 91122031)
A cyanide-bridged Fei^III2Coll double zigzag chain, { [Fen1(bipy)(CN)4]2Con(btab)2}n [bipy=2,2'-bipyridine, btab=4,4'-(1,3-phen- ylene)-bis-4H-1,2,4-triazole] (1), was obtained with tetracyanometalate prec...
关键词:double-zigzag chain METAMAGNETISM single-chain magnets 
氰根桥连的Fe~ⅢMn~Ⅱ链中磁性作用的调控(英文)被引量:2
《无机化学学报》2015年第7期1460-1466,共7页郑慧 徐杨 段春迎 
国家自然科学基金(No.91122031)资助项目
基于三氰构筑单元合成了两个氰基桥联的FeⅢ-MnⅡ一维链,{[Fe(Tp)(CN)3]2[Mn(bib)]}·CH3OH·2H2O(1)和{[Fe(pzTp)(CN)3]2[Mn(bib)]}·3H2O(2)。1和2中的双之字链通过刚性的双齿配体固定排列方式并连接成二维结构,链内FeⅢ和MnⅡ之间的...
关键词:氰基 之字链 双齿配体 磁相互作用 
微相分离理论在金属有机框架化合物中的应用:基于Ni(Ⅱ)和蒽醌四羧酸(H_4AQTC)的配位聚合物的研究(英文)
《无机化学学报》2014年第9期1985-1993,共9页丁刘镠 陈琪 盛小利 王冬妮 芦昌盛 
国家自然科学基金(No.21021062和91122031);江苏省自然科学基金(No.BK2011550)资助项目
通过使用不同尺寸的辅配体,我们合成了一系列以二价镍为金属离子,蒽醌四羧酸为主配体的金属有机框架化合物(1-5)。根据微相分离理论,通过选用不同尺寸的辅配体来调节聚合物的疏水体积比,我们得到具有不同结构的一系列配位聚合物。实...
关键词:微相分离理论 晶体结构 金属有机框架 蒽醌四羧酸 
2,2′-联嘧啶和二硫烯双核钴混配配合物的合成和晶体结构(英文)
《无机化学学报》2013年第8期1724-1732,共9页王冬妮 许多慧 丁刘镠 陈琪 芦昌盛 
grateful for the financial support of the National Basic Research program of China(2010CB923402);National Nature Science Foundation of China(NSFC:21021062 and 91122031);Jiangsu Science & Technology Department(BK2011550);the Center of Analysis and Determining of Nanjing University~~
以2,2′-联嘧啶(bpy)和马来二腈基阴离子(mnt)为配体合成了一个双核钴混配配合物(C4H9)4N2(Co(mnt)2)2(bpy)(1)(C56H78Co2N14S8)((C4H9)4N=tetrabutylammonium,mnt=maleonitriledithiolate and bpy=2,2′-bipyrimidyl),并用X-射线单晶...
关键词:混合配体 双核钴配合物 晶体结构 
Interesting Weak Interactions in Three Silver Coordination Polymers Based on Tetrafluorobenzenedicarboxylate and Benzonitrile Ligands被引量:2
《Chinese Journal of Structural Chemistry》2013年第7期969-974,共6页刘淑芹 李晓娟 狄玲 丁保君 张建军 
Supported by the NNSFC (21071025,91122031, 21107008);Doctoral Fund of Ministry of Education of China (20100041120021);the Fundamental Research Funds for the Central Universities (DUT12YQ04)
The assembly reactions of o- (or m-, or p-) tetrafluorobenzenedicarboxylic acid (denoted as o-H2L, m-H2L and p-HzL, respectively), benzonitrile and Ag+ ion led to three compounds: [Ag2(PhCN)2(o-HL)2]n (1),...
关键词:coordination polymers crystal structure weak interactions 
Synthesis and Characterization of a Tetranuclear [Sm_2Co_2] Heterometallic Compound
《Chinese Journal of Structural Chemistry》2012年第7期971-976,共6页杨文博 黄河清 李忠义 刘瑞斌 张建军 
Supported by the NNSFC (21071025, 91122031);Doctoral Fund of Ministry of Education of China (20100041120021);DUT (893127 and 851004)
A new tetranuclear square compound (H3O)[Sm2Co2(CDTA)2(DMF)2 (μ4-O) (H2O)6]ClO4 was synthesized through the assembly reaction of Co2+ , Sm3+ and trans-1,2-cclohexylenedinitrilotetraacetic acid (H4CDTA) ...
关键词:cluster compounds crystal structure HETEROMETALLIC 
Synthesis, structure, and magnetic properties of a cyanide-bridged Fe(Ⅲ)-Cu(Ⅱ) bimetallic double-zigzag chain with slow relaxation of the magnetization被引量:1
《Science China Chemistry》2012年第6期1018-1021,共4页DONG DaPeng ZHENG Hui ZHAO Liang ZHUANG PengFei LIU Tao HE Cheng DUAN ChunYing 
financial support from the National Natural Science Foundation of China (21101021, 91122031)
Using Bu4N[Fe(Tp*)(CN)3]- (Tp* = hydrotris(3,5-dimethylpyrazol-l-yl)borate) as the building block to react with Cun and N-methylimidazole, we obtained a one-dimensional (1D) beterobimetallic cyano-bridged chain, [Fe(T...
关键词:single chain magnet double-zigzag chain ferromagnetic coupling 
Synthesis, structure, and magnetic properties of a cyanide-bridged Fe(Ⅲ)-Cu(Ⅱ) bimetallic double-zigzag chain with slow relaxation of the magnetization被引量:1
《中国科学:化学》2012年第6期918-919,共2页DONG DaPeng ZHENG Hui ZHAO Liang ZHUANG PengFei LIU Tao HE Cheng DUAN ChunYing 
Using Bu4N[Fe(Tp*)(CN)3]- (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) as the building block to react with CuII and N-methylimidazole, we obtained a one-dimensional (1D) heterobimetallic cyano-bridged chain, [Fe(...
关键词:铁磁耦合 晶体结构 磁学性质 磁化 松弛 氰化物 双金属 N-甲基咪唑 
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