Supported by the National Natural Science Foundation of China (Grant Nos. 20771057, 20721002 and 20631030);the Major State Basic Research Develop-ment Program (Nos.2006CB806104 and 2007CB925102)
Two cyano-bridged heterobimetallic coordination polymers,[{Mn(dpa)2}2W(CN)8·CH3CN·4H2O]n(1)(dpa = 2,2'-dipyridylamine) and [Mn2(H2O)4{W(CN)8}·3H2O]n(2),have been synthesized and characterized structurally and magne...