国家重点基础研究发展计划(2010CB732300)

作品数:33被引量:320H指数:9
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相关作者:郭杨龙卢冠忠詹望成郭耘龚学庆更多>>
相关机构:华东理工大学南京大学中国科学院生态环境研究中心浙江中烟工业有限责任公司更多>>
相关期刊:《Journal of Rare Earths》《Science China Chemistry》《无机化学学报》《稀有金属》更多>>
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Effect of hydration on the surface basicity and catalytic activity of Mg-rare earth mixed oxides for aldol condensation
《Journal of Rare Earths》2018年第4期359-366,共8页Zheng Wang Pascal Fongarland Guanzhong Lu Wangcheng Zhan Nadine Essayem 
Project supported by National Basic Research Program of China(2010CB732300);111 Project(B08021);China Scholarship Council for the Joint-Training Scholarship Program with Institut de Recherches sur la Catalyse et l'Environnement de Lyon(IRCELYON)and Universite Claude Bernard Lyon 1(UCBL1)
Magnesium and rare earth mixed oxides(Mg3 REOx(RE=La, Y. Ce)) were prepared and characterized by Xray diffraction(XRD), N_2 adsorption-desorption, infrared spectra and microcalorimetry of CO_2. The results revea...
关键词:Mg-rare earth mixed oxide Hydration treatment Water tolerance Aldol condensation Solid base catalyst Rare earths 
含氟镧铈复合氧化物的制备、结构及性能研究被引量:2
《中国稀土学报》2017年第1期83-91,共9页杨晓宾 王筠松 郭耘 郭杨龙 王丽 詹望成 卢冠忠 
科技部973计划项目(2010CB732300)资助
La,Ce是丰度最高的稀土元素,主要用于催化和抛光材料。研究了从稀土盐到含F的La-Ce复合氧化物的制备过程,以及La/Ce比例、氟化过程、干燥过程及焙烧温度等对制备的含氟镧铈复合氧化物结构、粒径和形貌的影响。结果表明,用Na F 90℃氟化2...
关键词:含F的La-Ce复合氧化物 制备 喷雾干燥 形貌 抛光性能 
The synthesis of Co-doped SAPO-5 molecular sieve and its performance in the oxidation of cyclohexane with molecular oxygen被引量:8
《Chinese Journal of Catalysis》2016年第2期273-280,共8页校准 詹望成 郭耘 郭杨龙 龚学庆 卢冠忠 
supported by the National Basic Research Program of China(2010CB732300);the National Natural Science Foundation of China(21103048)~~
Silicoaluminophosphate(SAPO) molecular sieves doped with cobalt(Co-SAPO-5) were synthesized hydrothermally with different concentrations of Co.Each sample was characterized by X-ray diffraction,N2 adsorption-desor...
关键词:SAPO-5 molecular sieve COBALT CYCLOHEXANE Selective oxidation OXYGEN 
Solvent-free selective oxidation of cyclohexane with molecular oxygen over manganese oxides:Effect of the calcination temperature被引量:2
《Chinese Journal of Catalysis》2016年第1期184-192,共9页吴明周 詹望成 郭耘 王筠松 郭杨龙 龚学庆 王丽 卢冠忠 
supported by the National Basic Research Program of China(973 Program,2010CB732300);the National Natural Science Foundation of China(21103048)~~
The effects of calcination temperature on the physicochemical properties of manganese oxide catalysts prepared by a precipitation method were assessed by X-ray diffraction,N2 adsorption-desorption,X-ray photoelectron ...
关键词:Manganese oxide catalyst Selective oxidation of cyclohexane OXYGEN Calcination temperature Solvent-free reaction 
Epoxidation of propylene by molecular oxygen over unsupported AgCu_x bimetallic catalyst被引量:6
《Rare Metals》2015年第7期477-490,共14页Xiang Zheng Yang-Long Guo Yun Guo Qing Zhang Xiao-Hui Liu Li Wang Wang-Cheng Zhan Guan-Zhong Lu 
financially supported by the National Basic Research Program of China (No. 2010CB732300)
The unsupported Cu and Ag catalysts with different oxidation states were prepared, and their catalytic performances for propylene epoxidation were investigated.The metallic Cu catalyst exhibits much higher catalytic a...
关键词:Epoxidation of propylene Propylene oxide MOLECULAR 
Realization approach of Pd-only three-way catalysts with high catalytic performance and thermal stability被引量:1
《Science China Chemistry》2015年第1期123-130,共8页Yutao Ren Qun Shen Yun Guo Yanqin Wang Yanglong Guo Xueqing Gong Guanzhong Lu 
financially supported by the National Basic Research Program of China(2010CB732300);the National Natural Science Foundation of China(21273150);the National High Technology Research and Development Program of China(2011AA03A406)
Pd-only three-way catalyst (TWC), Pd supported on washcoating (the mixture of alumina and Ce-Zr solid solution)/cordierite, was prepared and its catalytic performance and the operation window (2-value) at 450 ℃...
关键词:three-way catalyst Pd-only catalyst catalyst preparation mixed surfactants high thermal stability 
氨基功能化MCM-48介孔材料的制备及选择性吸附卷烟主流烟气中氰化氢的性能被引量:2
《化学世界》2014年第11期650-654,共5页沈凯 夏倩 盛培秀 唐荣成 徐建 刘金莉 李霞 储国海 周国俊 詹望成 卢冠忠 郭杨龙 
国家973计划项目(2010CB732300);国家烟草专卖局资助项目(110201001004)
以纯硅MCM-48为原料合成了表面氨基功能化的MCM-48材料,进行了X射线衍射(XRD)、氮气吸附、SEM扫描电镜和FT IR红外光谱等表征。FT IR和元素分析的结果表明,3-氨基丙基三乙氧基硅烷通过与纯硅MCM-48表面的Si-OH基团反应,使氨基嫁接在纯硅...
关键词:介孔二氧化硅 氨基 选择性 氰化氢 
稀土催化材料的应用及研究进展被引量:29
《催化学报》2014年第8期1238-1250,共13页詹望成 郭耘 龚学庆 郭杨龙 王艳芹 卢冠忠 
国家重点基础研究发展计划(973计划,2010CB732300);国家高技术研究发展计划(863计划,2012AA111717);中央高校基本科研业务费专项资金(WK1214007);国家自然科学基金(21273150,21103048).
稀土元素具有未充满电子的4f轨道和镧系收缩等特征,当用作催化剂的活性组分或载体时常常表现出独特的催化性能.稀土催化材料的研究和发展为La和Ce等高丰度轻稀土元素的高质、高效利用提供了有效的途径.目前稀土催化材料在石油化工、化...
关键词:稀土催化材料 环境保护 清洁能源 密度泛函理论计算 氧化铈催化 
钒氧化物催化CO_2氧化异丁烷脱氢的研究(英文)被引量:4
《催化学报》2014年第8期1329-1336,共8页袁瑞雪 李杨 闫浩兵 王欢 宋健 张中申 樊卫斌 陈建刚 刘忠文 刘昭铁 郝郑平 
supported by the National Basic Research Program of China (973 Program,2010CB732300);the National Natural Science Foundation of China (21376146, 21306111,21337003)~~
采用溶胶-凝胶法制备了一系列钒氧化物催化剂,并用于CO2氧化异丁烷脱氢反应.采用X射线衍射、低温N2吸附-脱附、O2程序升温氧化、程序升温表面反应和原位傅里叶变换红外光谱等方法研究了催化剂的性质.反应结果表明,尽管所有钒氧化物催化...
关键词:异丁烷 氧化脱氢反应 二氧化碳 五氧化二钒 三氧化二铝 
KCl对Cu-K-La/γ-Al_2O_3催化剂上HCl氧化反应性能的影响(英文)被引量:6
《催化学报》2014年第8期1359-1363,共5页冯看卡 李晨威 郭杨龙 詹望成 马斌全 陈斌武 袁茂全 卢冠忠 
supported by the National Basic Research Program of China (973 Program, 2010CB732300);Commission of Science and Technology of Shanghai Municipality (13521103402);Shu Guang Project of Shanghai Municipal Education Commission and Shanghai Education Development Foundation (10SG30)~~
采用等体积浸渍法制备了Cu-K-La/γ-Al2O3催化剂,考察了KCl对该催化剂催化HCl氧化制Cl2反应性能的影响.当KCl的负载量为5 wt%时,Cu-K-La/γ-Al2O3催化剂表现出较好的催化活性和稳定性,可在较大的原料气空速变化范围内使用.在0.1 MPa,360...
关键词:氯化氢 催化氧化 氯气 铜基催化剂 氯化钾 
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