supported by the National Natural Science Foundation of China (20571035);the Ministry of Education,Singapore through NUS (FRC Grant No. R143-000-371-112)
The compound [Cu2(bpy)2(PDIAla)(H2O)2](ClO4)2·H2O(H2PDIAla = N,N'-(p-xylylene)dialanine,bipy = 2,2'-bipyridine) 1 has been synthesized and structurally determined by single-crystal X-ray diffraction,ele...
Project supported by the National Natural Science Founclation of China (No. 20571035), the Gansu Natural Science Foundation of China (No. 3ZS051-A25-003).Acknowledgement The authors are grateful to the Instrumental Analysis and Research Center of Lanzhou University and State Key Laboratory of Applied 0rganic Chemistry for providing instrumentation facilities.
A series of chiral salen-Mn(Ⅲ) complexes featuring two tertiary amine units were synthesized and employed in the enantioselective epoxidation of unfunctionalized alkenes in the presence of pyridine N-oxide and 2,6-...