the National Natural Science Foundation of China(Project No.20072033);Specialized Research Fund for the Doctoral Program of Higher Education of China.
Enamines, promoted by the samarium/samarium diiodide mixed reagent, were synthesized via the cross-coupling of thioamides and diarylketones in good yields.
the National Natural Science Foundation of China(Project No.20072033);the NSF of Zhejiang Province for financial support.
1-(β-Hydroxyalkyl)-l,3,4-oxadiazole derivatives were synthesized via reductive addition reactions of 2-chloromethyl-l,3,4-oxadiazole with carbonyl compounds under mild conditions promoted by SmI2.
the National Natural Science Foundation of China(Project No.20072033);the NSF of Zhejiang Province,China for financial support
One-pot reaction of aldehydes, ?haloketones and (phenylsulfonyl)acetonitrile promoted by SmI3 proceeded smoothly to give 1-cyano-1-phenylsulfonyl-2-aryl-3-aroyl-propane derivatives in moderate to good yields.
National Natural Science Foundation of China (Project No. 20072033) and Natural Science Foundation of Zhejiang province for financial support.
The intermolecular coupling of a nitro group with a cyano group mediated by a Sm(Hg) amalgam prepared from metal samarium powder and catalytic mercury dichloride was studied.