supported by the National Natural Science Foundation of China(No.22001085);Shandong Provincial Natural Science Foundation(No.ZR2021QB148);Fundamental Research Funds for the Central Universities(No.HUST:2023JCYJ001);Research Institute of Zhejiang Sci-Tech University in Longgang(No.LGYJY2021013)for financial support。
C(sp^(2))-H amination represents an attractive approach for the synthesis of enamines,which is intrinsically associated with the challenge of controlling of stereochemistry and primarily relying on transition-metal ca...
This work was supported by the Fundamental Research Funds for the Central Universities(YJ201805,YJ201864).
Asymmetric catalytic hydrogenations of imines and enamines with chiral transition-metal complexes bearing chiral ligands are among the most green and powerful approaches for the elaboration of chiral amine structures ...
Supported by the Natural Science Foundation of Shaanxi Province of China(No. 20093M2011), and the Innovation Founda- tion of Postgraduate Cultivation of Shaanxi Normal University of China(No. 2008CXB009).
A new method for the synthesis of functional enamines from β,β-dicyanostyrene derivatives and N-bromosaccharin(NBSA) was developed. In the presence of Na2CO3, the the reaction of β,β-dicyanostyrene derivatives w...
Organophosphorus compounds are essential structures in modern pharmaceutical, agrochemical, and material sciences. The development of new and efficient methods for the synthesis of C-P bonds has been an important focu...
The authors thank the National Key Research and Development Program of China (2016YFA0602900) and the National Natural Science Foundation of China (21490572 and 21420102003) for financial support.
Herein, two efficient palladium-catalyzed intermolecular oxidative coupling reactions of (Z)-enamines with isocyanides via selective β-C(sp2)-H and/or C=C bond cleavage have been developed, leading to controllabl...
Supported by the National Natural Science Foundation of China(Nos.20902001, 21102001), the Natural Science Foundation of the Educational Department of Anhui Province, China(No.KJ2014A013), the "211" Project of Anhui University(China) and the Doctor Research Start-up Fund of Anhui University(China).
An efficient, atom-economic and green approach to synthesizing enamines was developed by intermolecular hydroamination of activated alkynes with high yields under catalyst- and solvent-free conditions. β-Dimethylamin...
support of this work by Baoji University of Arts and Sciences(No.ZK15046).
An intermolecular two C-C bond formation procedure for the synthesis of carbocycles mediated by hyperva-lent iodine(III)reagents was developed.This metal free protocol provided a new approach for the synthesis of use-...
NSFC(No.21062014);the‘‘211’’Project in Ningxia University for financial support
The selective transalkylation of N-methyl tertiary amines with 3,4-dibromobutenolides is described. The N-methyl group of the parent tertiary amines was replaced by alkenyl units of the butenolides; and a series of bu...
support from the National Natural Science Foundation of China(20972051);the Science and Technology Commission of Shanghai Municipality(08430703900 & 08431901800);the 111 Project(B07023);East China University of Science & Technology
An unprecedented acetic acid-catalyzed efficient access to N-alkylpyrroles from reaction of 4-hydroxy-L-proline with a variety of aldehydes has been achieved in good to excellent yields under mild reaction conditions.
the financial support from the National Science Foun-dation (CHE-1057569,W. W.);the China 111 Project (B07023,J. L. and W. W.);the National Natural Science Foundation of China (20972051,X. Y.-H.);the Science and Technology Commission of Shanghai Mu-nicipality (08430703900 & 08431901800,X. Y.-H.)
A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to (E) selective a, β-unsamrated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to imin...