国家自然科学基金(20772005)

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Theoretical insights into the [4+2]/retro [4+2] cycloaddition approach to the synthesis of biaryls and polycyclic aromatics
《Science China Chemistry》2013年第5期633-640,共8页LI XinYao XU JiaXi 
supported by the National Natural Science Foundation of China (21172017, 20972013 and 20772005);the specialized Research Fund for the Doctoral Program of Higher Education, Ministry of Education of China (20110010110011);"CHEMCLOUD COMPUTING " of Beijing University of Chemical Technology
A domino [4+2]/retro [4+2] cycloaddition process of cyclohexadienes with arylethynes or benzyne providing access to biaryls and polycyclic aromatics has been studied theoretically using density functional theory calcu...
关键词：[4+2]/retro [4+2] cycloaddition BIARYLS polycyclic aromatics regioselectivity DFT study 
Stereoselective synthesis of cis- and trans-4-acyl-β-lactams from vicinal diketones and ketoaldehydes
《Science China Chemistry》2011年第11期1711-1717,共7页WANG ZhiXin XU JiaXi 
the support from the National Natural Science Foundation of China (20972013 and 20772005);Beijing Natural Science Foundation (2092022);the Fundamental Research Funds for the Central Universities (ZZ1020);the Doctoral Fund of Ministry of Edu-cation of China (200800100010)
4-Acyl-β-lactams are important synthetic intermediates in both pharmaceutical and organic chemistry. Cis- and trans-4-acyl-β- lactams were synthesized stereoselectively from vicinal diketones via the formation of bu...
关键词：4-acyl-β-lactam DIIMINE DIKETONE imine ketoaldehyde Β-LACTAM stereoselectivity 
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