Supported by the 973 Program (2007CB815301 and 2006CB932904);the National Natural Science Foundation of China (20333070, 20673118, 20871114);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006J0014, 2006F3132)
A chiral salency complex,[Mn(Salency)(H2O)2](PF6)·2H2O 1(Salency =(R,R)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine),has been prepared by the reaction of Mn(CH3COO)3·2H2O with Salency and NH4PF6,and...
supported by the 973 Program (2007CB815301 and 2006CB932904);the National Natural Science Foundation of China (20333070, 20673118, 20871114);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006L2005, 2006J0014, 2006F3132)
A new thiostannate,[tmdpH2]Sn3S7 1(tmdp = 4,4'-trimethylenedipiperidine),has been synthesized under solvothermal conditions and characterized by elemental analysis,IR spectroscopy,and single-crystal X-ray diffracti...
Supported by the 973 Program (2007CB815301 and 2006CB932904);the National Natural Science Foundation of China (20333070, 20871114 and 20673118);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006F3132 and 2007J0171)
Two cyanide bridged trinuclear compounds [Fe(bpy)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·DMF 1 and [Fe(Phen)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·2CH3CN·4H2O 2 (Bpy = 2,2'- bipyridine, Phen = 1,10-phenanthroline, C...
the grants from 973 Program (2007CB815301 and 2006CB932904);the National Natural Science Foundation of China (20333070 and 20673118);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006L2005, 2006F3132 and 2007J0171)
Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylformamid...
Supported by the National Natural Science Foundation of China(Nos.20571032 and 20333070).
Two new supramoleeular polymers [ M (2-NH2 py)2 (ox) ] [ M = Co (1), Ni (2) ; 2-NH2py = 2-aminopyridine; ox = oxalate ] were hydrothermally synthesized and characterized by elemental analyses, IR and single-cr...
This work was supported by the State Key Laboratory of Structural Chemistry, the Ministry of Science and Technology of China (001CB108906);the National Natural Science Foundation of China (20333070)
The organic-inorganic hybrid polymer [Mn(mbbimb)2(1,5-nds)]n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4,structure analysis indicates that 1 crys...
This work was supported by the State Key Laboratory of Structural Chemistry, the Ministry of Science and Technology of China (001CB108906) ;the National Natural Science Foundation of China (20333070)
The self-assembly reactions of M^ⅡCl2 (M = Ni, Co) with the flexible bix ligand [bix = 1,4-bis(imidazole-1-ylmethyl)benzene] yielded a 2D network [N^Ⅲ(bix)2Cl2]n 1 and a 1D chain [Co^Ⅱ(bix)Cl2]n 2. Their cr...
This work was supported by the 973 program of the MOST (001CB108906);the National Natural Science Foundation of China (20425313, 90206040, 20333070, 20303021);the Natural Science Foundation of Fujian Province (2005HZ01-1)and the Chinese Academy of Sciences
A novel copper molybdate with mixed ligands, [{(Cu·phen)e(tp)} {(Cu·phen·H2O)2(tp)} {Mo4O14}(phen = 1,10-phcnanthroline, tp = tercphthalate) 1, has been hydrothermally synthesized and structurally charact...
the State Key Laboratory of Structural Chemistry, the 973 program (2006CB932900);the NNSFC (20673118, 20333070, 90206040 and 90406024);NSF of Fujian Province (2006J0014, 2004HZ01-1, and 2005HZ01-1)
The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd(NO3)2 affords a novel 2D cadmium tetrazolyl-benzoate, {Cd(tzbz)(H2O)}n (H2tzbz is 2-(5-tetrazolyl)-benzoate). The tzbz ligand i...
This work was supported by the State Key Laboratory of Structural Chemistry, the National Ministry of Science and Technology of China (001CB1089);the NNSFC (20333070, 90206040 and 90406024) ;NSF of Fujian Province (2004J041, 2004HZ01-1, and 2005HZ01-1)
The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of CuC12, 2,2'-bipyridine and H2O affords a novel dinuclear copper(Ⅱ)-ditetrazolate, [Cu(bpy)- (pdtz)]2 (Hpdtz = 5,5"-1,2-phenylene-d...