国家自然科学基金(20171036)

作品数:39被引量:44H指数:4
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相关作者:高胜利陈三平史启祯杨旭武焦宝娟更多>>
相关机构:西北大学西安近代化学研究所中国工程物理研究院陕西理工大学更多>>
相关期刊:《应用化学》《Chemical Research in Chinese Universities》《Journal of Rare Earths》《Science China Chemistry》更多>>
相关主题:PHEN固态配合物THERMOCHEMISTRY标准生成焓RE更多>>
相关领域:理学医药卫生自然科学总论生物学更多>>
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Lu(Et_2dtc)_3(phen)的生成反应焓变、摩尔热容和恒容燃烧能测定(英文)被引量:1
《无机化学学报》2006年第3期533-541,共9页葛红光 陈三平 谢钢 扬旭武 高胜利 史启祯 
国家自然科学基金(No.20171036,No.20471047);陕西省自然科学基金(No.2003B19);国家博士后基金资助项目。
A ternary solid complex Lu(Et2dtc)3(phen) has been obtained from the reaction of hydrated lutetium chloride with sodium diethyldithiocarbamate (NaEt2dtc), and 1,10-phenanthroline (o-phen·H2O) in absolute ethanol. IR ...
关键词:Lu(Et2dtc)3(phen) 生成反应焓变 热容 恒容燃烧能 
Low-temperature Heat Capacity and Standard Molar Enthalpy of Formation of Potassium L-Threonate Hydrate K(C4H7O5)·H2O被引量:1
《Chinese Journal of Chemistry》2006年第2期187-192,共6页魏青 陈三平 高胜利 邸友莹 谭志诚 史启祯 
Project supported by the National Natural Science Foundation of China (No. 20171036), Education Committee of Shannxi Province (Nos. 01JK229, FF02328 and 2004B 10) and Postgraduate Foundation of China.
The solid potassium L-threonate hydrate, K(C4H7O5)·H2O, was synthesized by the reaction of L-threonic acid with aqueous potassium hydrogen carbonate and characterized by means of chemical and elemental analyses, IR...
关键词:potassium L-threonate hydrate low-temperature heat capacity adiabatic calorimetry rotary-bomb combustion calorimetry standard molar enthalpy of formation 
Measurements of Enthalpy Change of Reaction of Formation, Molar Heat Capacity and Constant-Volume Combustion Energy of Solid Complex Yb(Et_2dtc)_3(phen)被引量:2
《Journal of Rare Earths》2006年第2期155-162,共8页宋伟明 胡奇林 常旋 陈三平 谢钢 高胜利 
ProjectsupportedbytheNationalNaturalScienceFoundationofChina(20171036;20471047);theNationalNaturalScienceFoundationofShaanxi(2003B19;FF05201andFF05203)Province;theEducationDepartmentFoundationofShaanxi(05JK291)andtheFoundationofNingxiaGasKeyLaboratory
A ternary solid complex Yb(Et2dtc)3(phen) was obtained from the reaction of hydrous ytterbium chloride with sodium diethyldithiocarbamate (NaEt2dtc), and 1, 10-phenanthroline (o-phen·H2O) in absolute ethanol....
关键词:hydrous ytterbium chloride sodium dinedithiocarbamate (NaEt2dtc) 1  10-phenanthroline (o-phen·H2O) THERMOCHEMISTRY rare earths 
Standard energies of combustion and standard enthalpies of formation for the complexes RE (Et_2dtc)_3(phen) (RE = Ho,Er,Tm,Yb,Lu)
《Rare Metals》2005年第4期301-305,共5页WEI Qing CHEN Sanping YANG Xuwu GAO Shengli SHI Qizhen 
[This work was financially supported by the Natural Science Foundation of China (No. 20171036), the Natural Science Foundation of Shaanxi Province (Nos. 01JK229, FF02328 and 05JK291) and Postgraduate Foundation of China.]
The treatment of RECl3.xH2O (RE = Ho, Er, Tm, Yb, Lu; x = 3-4) with sodium diethyldithiocarbamate (NaEtEdtc-3H2O) and 1,10-phenanthroline hydrate (o-phen.H2O) in absolute ethanol yielded five ternary solid compl...
关键词:THERMOCHEMISTRY combustion energy CALORIMETER RE(Et2dtc)3(phen) standard enthalpy of formation 
Thermokinetics on the reaction of formation of Dy[(C_(5)H_(8)NS_(2))_(3)(C_(12)H_(8)N_(2))]被引量:1
《Science China Chemistry》2005年第z1期74-78,共5页GAO Shengli CHEN Sanping JIAO Baojuan SHUAI Qi SHI Qizhen 
supported by the National Natural Science Foundation of China(Grant No.20171036);Science Foundation of Shaanxi Province(No.2003B19).
The enthalpy change of formation of the reaction of hydrous dysprosium chloride meter. Thermodynamic parameters (the activation enthalpy, the activation entropy and the activation free energy), rate constant and kinet...
关键词:HYDROUS DYSPROSIUM chloride  ammonium pyrrolidinedithiocarbamate (APDC)  1 10-phenanthroline(o-phen)  microcaiorimetry  thermochemistry. 
Thermal decomposition of Pr[(C_(5)H_(8)NS_(2))_(3)(C_(12)H_(8)N_(2))]
《Science China Chemistry》2005年第z1期83-87,共5页GUO Pengjiang,JIAO Baojuan,CHEN Sanping,HU Rongzu,GAO Shengli & SHI Qizhen Department of Chemistry,Northwest University Shaanxi Key Laboratory of Physico-lnorganic Chemistry,Xi’an 710069,China Department of Mathematics,Northwest University,Xi’an 710069,China Xi’an Modern Chemistry Research Institute,Xi’an 710065,China 
supported by the National Natural Science Foundation of China(Grant No.20171036);Education Committee of Shannxi Province(No.01JK229)
The thermal behavior of the complex Pr[(C5H8NS2)3(C12H8N2)] in a dry nitrogen flow was examined by TG-DTG analysis. The TG-DTG investigations indicated that Pr[(C5H8NS2)3-(C12H8N2)] was decomposed into Pr2S3 and depos...
关键词:Pr[(C5H8NS2)3(C12H8N2)]  thermal analysis  kinetics  noncrystal  characteristics. 
Determination of combustion energies and the standard enthalpies of formation for the complexes of RE(Et_(2)dtc)_(3)(phen)被引量:1
《Science China Chemistry》2005年第z1期88-92,共5页YANG Xuwu ZHU Li CHEN Sanping GAO Shengli SHI Qizhen 
supported by the National Natural Science Foundation of China(Grant No.20171036);Education Committee of Shaanxi Province(No.01JK229);Northwest University(02NW02)
Solid complexes,RE(Et_(2)dtc)_(3)(phen)(RE=La,Pr,Nd,Sm-Lu),were synthesized with sodium diethyldithiocarbamate(NaEt_(2)dtc3H_(2)O),1,10-phenanthroline(o-phen·H_(2)O)and hydrated lanthanide chlorides in absolute ethan...
关键词:thermochemistry combustion energies calorimeter RE(Et_(2)dtc)_(3)(phen) standard enthalpies of formation 
Thermochemical Study of Coordination of Holmium Chloride Hydrate with Diethylammonium Diethyldithiocarbamate被引量:1
《Chemical Research in Chinese Universities》2004年第6期766-770,共5页ZHAO Feng-qi CHEN San-ping JIAO Bao-juan REN Yi-xia GAO Sheng-li SHI Qi-zhen 
the National Natural Science Foundation of China(No. 2 0 1710 36 ) and the Natural Science Foundation ofShaanxi Province(No.2 0 1710 36
The complex of holmium chloride hydrate with diethylammonium diethyldithiocarbamate(D-DDC) was synthesized via mixing their solutions in absolute alcohol under a dry N 2 atmosphere. The elemental and chemical analyse...
关键词:Holmium chloride hydrate Diethylammonium diethyldithiocarbamate(D-DDC) Microcalori-metric method THERMOCHEMISTRY 
RE(C_5H_8NS_2)_3(C_(12)H_8N_2)(RE=La,Pr,Nd,Sm)的标准摩尔生成焓测定研究被引量:7
《化学学报》2004年第22期2233-2238,共6页孟祥鑫 高胜利 陈三平 杨旭武 谢钢 史启祯 
国家自然科学基金 (No .2 0 1 71 0 36);陕西省教育厅专项基金 (No.0 1JK2 2 9)资助项目
在无水乙醇中 ,使低水合氯化稀土 (RE =La ,Pr ,Nd ,Sm)与吡咯烷二硫代氨基甲酸铵 (APDC)和 1,10 邻二氮菲 (o phen·H2 O)反应 ,制得其三元固态配合物 .用化学分析和元素分析确定它们的组成为RE (C5H8NS2 ) 3 (C12 H8N2 ) (RE =La ,Pr...
关键词:稀土氯化物 吡咯烷二硫代氨基甲酸铵 1 10-邻二氮菲 标准摩尔燃烧焓 标准摩尔生成焓 固态配合物 恒容燃烧热 
三元配合物Er(Et_2dtc)_3(phen)的热化学性质被引量:2
《应用化学》2004年第12期1211-1216,共6页朱丽 杨旭武 焦宝娟 帅琪 高胜利 史启祯 
国家自然科学基金 ( 2 0 1710 3 6);陕西省教育厅专项基金 ( 0 1JK2 2 9)资助项目
在无水乙醇中 ,用铜试剂 (NaEt2 dtc·3H2 O)和邻菲咯啉 (o phen·H2 O)与水合氯化铒 (ErCl3 ·3 4 6H2 O)作用 ,制得三元固态配合物。化学分析和元素分析确定其组成为Er(Et2 dtc) 3 (phen)。IR光谱研究表明 ,配合物中Er3 + 与NaEt2 dt...
关键词:Er(Et2dtc)3(phen) 微量热法 热动力学 恒容燃烧能 标准摩尔生成焓 
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