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《无机化学学报》: 作品数：9241被引量：30015H指数：41; 导出分析报告; 主办单位：中国化学会; 最新期次：2025年3期更多>>; 发文主题：晶体结构配合物英文荧光性质配位聚合物更多>>; 发文领域：理学化学工程一般工业技术电气工程更多>>; 发文作者：邝代治冯泳兰张复兴陆路德汪信更多>>; 发文机构：南京大学中国科学院南开大学浙江大学更多>>; 发文基金：国家自然科学基金国家重点基础研究发展计划江苏省自然科学基金国家教育部博士点基金更多>>

双金属掺杂多孔碳正极材料的合成与电化学性能: 《无机化学学报》2025年第3期509-520,共12页曹翔宇张嘉盈丰赟申林坤张秀玲闫娟枝; 山西省基础研究计划项目(No.202103021223003);国家级大学生创新创业训练项目(No.20241387);省级大学生创新创业训练项目(No.20241437)资助。; 利用水热反应制备了葡萄糖缩聚物包覆铁氰化钴晶体的复合前驱体,经过碳化、酸刻蚀和硫负载,最终获得一种双金属(Co、Fe)及氮掺杂的多孔碳/硫复合材料(e-CF@NPC/S,其中CF表示CoFe合金,NPC表示氮掺杂的多孔碳)。进而通过改变形成核壳的原...; 关键词：金属掺杂锂硫电池正极材料复合材料核壳结构

稻壳基活性炭负载MgO复合材料在对称超级电容器中的应用: 《无机化学学报》2025年第3期521-530,共10页隋光辉程岩岩; 江西省教育厅科技项目(No.GJJ202616);南昌师范学院校级科技项目(No.23XJZR02)资助。; 将稻壳经低温炭化、KOH高温活化处理,得到无定形活性炭(AC)材料,再采用MgO原位负载的方法制备一系列炭负载MgO复合材料(MgO/AC)。采用X射线衍射(XRD)、激光共聚焦拉曼光谱、X射线光电子能谱(XPS)、扫描电子显微镜-X射线能谱(SEM-EDS)和...; 关键词：MgO负载活性炭复合电极对称超级电容器能量密度

Z型异质结β-Bi_(2)O_(3)柱撑CoAl层状双金属氢氧化物复合材料的构建及其光催化降解性能: 《无机化学学报》2025年第3期531-539,共9页张亚平吴桐辰郑云林碧洲; 国家自然科学基金(No.21978246);福建省自然科学基金(No.2014J01050,2023J01115)资助。; 采用剥离-重组法,以剥离的CoAl层状双金属氢氧化物(CoAl-LDH)纳米片为主体,β-Bi_(2)O_(3)纳米胶粒为客体,成功制备了β-Bi_(2)O_(3)柱撑CoAl-LDH复合材料(β-Bi_(2)O_(3)/CoAl-LDH)。运用X射线衍射、透射电子显微镜、紫外可见吸收光谱...; 关键词：光催化剂氧化铋层状双羟基氢氧化物柱撑材料 Z型异质结四环素

A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells: 《无机化学学报》2025年第3期540-548,共9页ZHANG Linfang YIN Wenzhu YIN Gui; financially supported by the Natural Science Foundation of Jiangsu Province(Grant No.BK20241181);the State Key Laboratory of AnalyticalChemistry for Life Science,School of Chemistry and Chemical Engineering,Nanjing University(Grant No.SKLACLS2419)。; Using 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran(TCF)as a near-infrared fluorescent chromophore,we designed and synthesized a TCF-based fluorescent probe TCF-NS by introducing 2,4-dinitrophenyl ether ...; 关键词：hydrogen sulfide near⁃infrared fluorescence probe cell imaging

Synthesis,structures,and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid: 《无机化学学报》2025年第3期549-560,共12页HOU Jimin LI Mengyang GONG Chunhua ZHANG Shaozhuang ZHAN Caihong XU Hao XIE Jingli; 国家自然科学基金(No.21771088)资助。; (2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under...; 关键词：bipyridyl ligands metal⁃organic frameworks photocatalytic degradation Knoevenagel condensation

Pr/N co-doped biomass carbon dots with enhanced fluorescence for efficient detection of 2,4-dinitrophenylhydrazine: 《无机化学学报》2025年第3期561-573,共13页SUN Xuehua MA Min LIU Jianting TIAN Rui CHAI Hongmei CUI Huali GAO Loujun; supported by the National Natural Science Foundation of China (Grant No.22063010);the Natural Science Foundation of Shaanxi Province (Grant No.2022QFY07-05);Yan'an Science and Technology Plan Project (Grants No.2022SLJBZ-002, 2023-CYL-193)。; We used the natural product chamomile as a carbon source to synthesize praseodymium(Pr) and nitrogen(N) co-doped biomass carbon dots(Pr/N-BCDs) with remarkable luminescence properties by one-step hydrothermal method.C...; 关键词：co⁃doped carbon dots 2 4⁃DNPH fluorescence detection

Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer: 《无机化学学报》2025年第3期574-586,共13页REN Jing YAN Ruikui CHEN Xiaoli CUI Huali YANG Hua WANG Jijiang; 国家自然科学基金(No.21763028);陕西省科技厅重点研发计划一般项目(No.2022NY-071)资助。; A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)O.The str...; 关键词：coordination polymer 4⁃(2 4⁃dicarboxylic phenoxyl)phthalic acid fluorescence sensing logic gate

Structure and magnetic properties of Mn(Ⅱ)coordination polymers regulated by N-auxiliary ligands: 《无机化学学报》2025年第3期587-596,共10页LIU Xiaxia MA Xiaofang GUO Luxia HAN Xianda FENG Sisi; 国家自然科学基金(No.21671124);山西工学院博士科研启动基金资助。; Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-...; 关键词：coordination polymers crystal structures binuclear Mnunit tetranuclear Mnunit MAGNETISM

In situ synthesis,crystal structure,and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold: 《无机化学学报》2025年第3期597-604,共8页WANG Zhaodong; A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazi...; 关键词：amide ligand copper complex single crystal structure C-N coupling magnetic characterization

A rhombic Dy_(4)-based complex showing remarkable single-molecule magnet behavior: 《无机化学学报》2025年第3期605-612,共8页HOU Yinling JI Jia YU Hong BIAN Xiaoyun GUAN Xiaofen QIU Jing REN Shuyi FANG Ming; 凯里学院校级规划课题(No.2022ZD07)资助。; A tetranuclear Ln(Ⅲ)-based complex:[Dy_(4)(dbm)_(4)(L)_(6)(μ_(3)-OH)_(2)]·CH_(3)CN(1)(HL=5-[(4-methylbenzylidene)amino]quinolin-8-ol,Hdbm=dibenzoylmethane)was manufactured and its structure was characterized in det...; 关键词：tetranuclear Dy(Ⅲ)complex Schiff base ligand crystal structure magnetic property single⁃molecule magnet

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