supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033);the National Natural Science Foundation of China(52073286,21875252,21701177);the Natural Science Foundation of Fujian Province(2006L2005)。
A new 3D terbium(Ⅲ)metal-organic network[Tb(HIMDC)(HCOO)(H_(2)O)]_(n)(complex 1)has been synthesized by Tb^(3+)ions coordinated with 4,5-imidazole dicarboxylic acid(H_(3)IMDC)and formic acid under solvothermal condit...
supported financially by Jiangsu Higher Education Institutions of China (18KJB150030)。
Enantiomerically pure lanthanide(Ⅲ)-based phosphonates are successfully synthesized by using(R)-or(S)-(1-phenylethylamino)-methylphosphonate acid(pempH2),namely,R-or S-[Tb3(pempH2)2(pempH)7]-Cl2·H2O(R-Tb or S-Tb),cr...
financially supported by Foundation of Fujian Educational Committee(JA14348)
A novel terbium(III) coordination polymer [Tb(C7H3NO4)(C6H4NO2)(H2O)] was successfully synthesized hydrothermally and characterized by single-crystal X-ray diffraction. The complex is of monoclinic, space group P21/c ...
Three new reactive ternary terbium complexes were synthesized with the first ligand of thenoyltri-(fluoroacetone) and the reactive secondary ligand such as maleic anhydride, undecenoic acid, oleic acid, and characteri...
A novel rare earth complex monomer Tb-Ca-PMDMBA(PMDMBA denotes pyromellitic dianhydride-modified Bisphenol A epoxy acrylate resin) was synthesized for the first time as following procedure. Firstly, Bisphenol A epox...
Project supported by the National Natural Science Foundation of China
The novel eomplexes of alkali and rare earth metal with periodate have been prepared for the first time. Chemical analysis indicates that the composition of the complexes is M_2LnIO_6·xH_2O(M=Li,Na,K;Ln=Pr, Tb),and a...