Thermal decomposition experiment of 5-(4-Pyridyl)tetrazolate(H4-PTZ)was carried out.The heat flow curve and reaction rate data under different heating rates were obtained.The characteristic parameters were obtained.Th...
Supported by NNSFC(No.21573236);the State Key Laboratory of Fine Chemicals(No.KF 1804);the Foundation of Ningde Normal University(No.2018Y04 and 2018Q105);the Natural Science Foundation of Fujian Province(No.2019J01839)
Urothermal method was firstly used to synthesize zeolitic tetrazolate-imidazolate frameworks. By using 2-imidazolidone hemihydrate(e-urea) as solvent, a new compound, namely ZTIF-17 with GIS topology, has been obtaine...
financial assistance from the National Natural Science Foundation of China(No.21241003);the Natural Science Basic Research of Shaanxi Province(No.2018JM2061);the Northwest University Graduate Innovation and Creativity Funds(No.YZZ17145)
A new coordination compound of Zn(NH3)3(AFT)2(1,ZnC6H13N17O2,AFT =4-amino-3-(5-tetrazolate)-furazan)was synthesized and characterized by elemental analysis and FT-IR spectrum.Its crystal structure was determined by X-...
Financial support of the ligand and MOFs synthesis in part by the Center for Gas Separations Relevant to Clean Energy Technologies;an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001015;part of the U.S. Department of Energy (DOE), ARPA-e (DE-AR0000249);DOENational Energy Technology Laboratory Award (DE-FE0026472);the Welch Foundation under award number A-1725;the Welch Endowed Chair to HJZ (A-0030) for support of the structural analyses;The X-ray diffractometers, and crystallographic computing systems in the X-ray Diffraction Laboratory at the Department of Chemistry, Texas A & M University were purchased with funds provided by the National Science Foundation (CHE-9807975, CHE-0079822, CHE-0215838);The FESEM acquisition was supported by the NSF (DBI-0116835);the VP for Research Office, and the TX Eng. Exp. Station. D. Liu and C. Zhong thank the supports of Natural Science Foundation of China (21136001, 21276008);National Key Basic Research Program of China (2013CB733503);D.L. also thanks the support of China Scholarship Council (201208110375) ;Beijing Higher Education Young EliteTeacher Project (YETP0486)
With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.
supported by the National Natural Science Foundation of China(No.21071099);Natural Science Foundation of Guangdong Province(No.2015A030313750);Characteristic Innovation Projects Guangdong Provincial Department of Education(Natural Science Category,2014KTSCX169)
Hydrothermal reactions of 3-cyanopyridine and Na N3 with Zn Cl_2 or Cd Cl_2·5/2H_2 O in the presence of 1,4-benzenedicarboxylic acid(H2bdc) yielded two new coordination polymers,{[Zn(3-ptz)(bdc)_(0.5)(H_2O)...
Partly supported by the Key Research Foundation of Wannan Medical College(WK2014Z06);Doctoral Starting up Foundation of Wannan Medical College(201219);the Foundation of Science and Technology Development of Shanghai(14ZR1447900)
One coordination polymer with bifunctional zwitterionic ligand bearing both carboxylate and tetrazolate groups, [Cd(L1)(N3)]n·n H2O(1, L1 = 1-(carboxylatomethyl)-4-(5-tetrazolato)pyridinium], has been in sit...
supported by the National Natural Science Foundation of China(21201023);the scientific research fund of Hubei Provincial Education Department(D20131202)
Reactions of 2-(2-benzoimidazolyl)acetonitrile and Na N3 with Zn SO4 or Zn Cl2 in the presence of nicotinic acid in the mixture of Et OH/H2 O afforded a mononuclear compound [Zn(L1)2](1) and a 1-D polymer [Zn(L...
supported by the US Air Force Office of Scientific Research (F49550-10-1-0521)
Zinc halide-complexed alkyl-bridged bi-heterocycles were obtained as zwitterions from the Click reaction of a series of N-cyanoalkyl-N-alkylimidazolium halide ionic liquids with sodium azide. Reaction optimization sho...