supported by the National Natural Science Foundation of China(Nos.52173005,21788102 and 21822102);the Ministry of Science and Technology of China(No.2021YFA1501600);the Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(No.2019B030301003);the Fundamental Research Funds for the Central Universities.
Multicomponent polymerizations(MCPs)are powerful tools to synthesize functional polymers with great structural diversity,low cost and high efficiency,which usually generate single polymer product.Herein,a robust one-p...
financially supported by the National Natural Science Foundation of China(No.21801002);the Overseas Students Innovation and Entrepreneurship Support Program Project of Anhui Province(No.2021LCX022);the Key R&D Projects in Anhui Province(No.2022i01020012);the Natural Science Foundation of Hefei(No.2022039)。
Branched polyolefins with controllable topology structures were generated from the chain-walking(co)polymerizations of ethylene,1-pentene(1P)and 2-pentene(2P)using Brookhart-typeα-diimine Ni(II)-based catalysts posse...
This research was made possible as a result of a generous grant from National Science Foundation of China(21822102,21774034,21490573,21490574,and 21788102);the Natural Science Foundation of Guangdong Province(2016A030306045 and 2016A030312002);the Innovation and Technology Commission of Hong Kong(ITC-CNERC14SC01)。
Selenium-containing polymers with fascinating functionalities such as stimuli-responsive property,enzyme mimics,antioxidant activity,promotion of immune-cell activity,anticancer activity,and controlled delivery proper...
financially supported by the National Natural Science Foundation of China (Nos. 21674130, 51873234);Natural Science Foundation of Guangdong Province (No. 2017A030310 349);Fundamental Research Funds for the Central Universities (No. 17lgjc02);PetroChina Innovation Foundation (No. 2017D-5007-0505)
Polymerizations of linear α-olefins(CnH2n, CH2=CH―R, R = Cn-2) catalyzed by early transition metals typically afford amorphous polymers with alkyl chains(Cn-2), while chain-straightening polymerizations of α-olefin...
Ionic polymerizations, including anionic and cationic polymerizations, constitute one of the most important sectors of chain growth polymerizations. The discovery of "living polymers" by Szwarc in anionic polymerizati...
financially supported by the National Basic Research Program of China(No.2015CB654700(2015CB654702));the National Natural Science Foundation of China(No.21801236)
A series of pyrazolylimine ligated Co(II) and Fe(II) complexes with general formula of(PhC=N(C_6H_3(R_1)2-2,6)(C_3 HN_2(R_2)2-3,5)MtCl_2(R_1 = Me, R_2 = H, Mt = Co(1 a), Fe(2 a); R_1 = Me, R_2 = Me, Mt = Co(1b), Fe(2b...
supported by the National Natural Science Foundation of China(51273187,21374107);the Fundamental Research Funds for the Central Universities(WK2060200012);the Program for New Century Excellent Talents in Universities(NCET-11-0882)
Multicomponent polymerizations have become powerful tools for the construction of sequence-defined polymers. Although the Passerini multicomponent reaction has been widely used in the synthesis of sequence-defined pol...
A new diamine containing sulfone,sulfide and amide groups was synthesized via a three-step reaction process. The nucleophilic substitution reaction of 4-aminothiophenol with 4-nitrobenzoyl chloride in the presence of ...
This work was supported by the National Natural Science Foundation of China (grant No. 20174034, 20274037).
A series of Ti/Mg supported catalysts are prepared by using ball-milled mixtures of MgCl2-ethanol adducts and NaCl as supports, and 1-hexene polymerizations catalyzed by the novel catalysts are studied. It is found th...