REGIOCONTROL

作品数:2被引量:3H指数:1
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相关期刊:《有机化学》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金广东省自然科学基金更多>>
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Regiocontrolled Rh(Ⅲ)-catalyzed C-C coupling/C-N cyclization mediated by distinctive 1,2-migratory insertion of gem-difluoromethylene allenes:Reaction development and mechanistic insight
《Chinese Chemical Letters》2023年第5期250-255,共6页Zhi Zhou Kaifeng Chen Yi Wang Xiuhua Zhong Shuang Lin Hui Gao Wei Yi 
the National Natural Science Foundation of China(NSFC,Nos.21877020,22007020);Natural Science Foundation of Guangdong Province(No.2019A1515010935);Science and Technology Program of Guangzhou(No.202102020615)for financial support on this study。
By developing gem-difluoromethylene allenes as viable partners,regiocontrolled Rh(Ⅲ)-catalyzed redoxneutral C-C coupling/C-N cyclization has been realized to build the pyridin-2(1H)-one motifs with the embedment of a...
关键词:Gem-difluoromethylene allenes C-H functionalization REGIOCONTROL Rhodium(Ⅲ)catalysis DFT calculations 
Small Peptides Catalyzed Direct Aldol Reactions of Aldehydes with Hydroxyacetone with Regiocontrol in Aqueous Media被引量:3
《有机化学》2004年第z1期41-42,共2页TANG,Zhuo YANG,Zhi-Hua CUN,Lin-Feng GONG,Liu-Zhu MI,Ai-Qiao JIANG,Yao-Zhong 
Very recently, we[1] found that L-proline amides and dipeptides acted as efficient catalysts for the asymmetric direct aldol reaction. We report here that L-proline-based peptides 1~5 can catalyze the aldol reactions ...
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