ARYLOXIDE

作品数：7被引量：4H指数：1
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相关领域：理学更多>>
相关作者：王佰全更多>>
相关机构：南开大学苏州大学更多>>
相关期刊：《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《Chinese Journal of Polymer Science》《Science Bulletin》更多>>
相关基金：国家自然科学基金江苏省“青蓝工程”基金国家重点基础研究发展计划国家科技支撑计划更多>>
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Living Polymerization of 1,3-Butadiene Catalyzed by Half-titanocene Complex Bearing Dibenzhydryl-substituted Aryloxide Ligand被引量：1
《Chinese Journal of Polymer Science》2017年第6期721-727,共7页Bo Dong Rui Zhuang Chun-yu Zhang Wen-jie Zheng He-xin Zhang Yan-ming Hu 孙广平 张学全 
financially supported by the National Basic Research Program of China(No.2015CB654700);the National Natural Science Foundation of China(No.U1462124);the National Key Technology R&D Program(No.2014BAE14B00)
Half-titanocene complexes bearing dibenzhydryl-substituted aryloxide ligands （2a-2d） were prepared. Among them, 2e adopted a three-legged distorted tetrahedral geometry evidenced by X-ray crystallography. The poly-1...
关键词：Half-titanocene complexes 1 3-BUTADIENE Thermal stability Living polymerization 
Ring-opening Polymerization of L-Lactide by an Anionic Cobalt（Ⅱ） Aryloxide被引量：2
《Chinese Journal of Chemistry》2012年第7期1474-1478,共5页袁春香 徐小平 张勇 纪顺俊 
Acknowledgement This work was partially supported by the NatxonaL Natural Science Foundation of China （Nos. 21042007, 21172162）, the Nature Science Basic Research of Jiangsu Province for Higher Education （No. 10KJB 150016）, the Priority Academic Program Development of Jiangsu Higher Education Institutions and Key Project in Science and Technology Innovation Cultivation Program of Soochow University.
The reaction of anhydrous CoCl2 with NaOAr （ArO=2,4,6-tri-tert-butylphenoxo） in THF at room temperature in 1 ： 3 molar ratio afforded anionic cobalt aryloxide [Na（THF）6][Co（OAr）3] （1）. The definite structure ...
关键词：ring-opening polymerization cobalt（Ⅱ） aryloxide SYNTHESIS L-LACTIDE 
Syntheses and Crystal Structures of Sm(OAr)+2(THF)+3·THF and Sm(OAr)_2(DME)_2 (Ar =C_6H_2-tert-Bu_3-2,4,6)被引量：1
《Chinese Journal of Structural Chemistry》2005年第10期1152-1156,共5页YUAN Fu-Gen ZHU Xue-Hua WENG Lin-Hong 
The project was supported by the Qinglan Foundation of Jiangsu Province (HB2001-27) and the Foundation of Educational Commission of Jiangsu Province (04KJD560171)
Reaction of SmI2（THF）x with 2 equivalents of NaOAr （Ar = C6H2-tert-Bu3-2,4,6） in THF affords a divalent complex of Sm（OAr）2（THF）yTHF 1 in 90.8% yield. Treatment of 1 with 1,2-dimethoxyethane （DME） leads to t...
关键词：DIVALENT SAMARIUM ARYLOXIDE AZOBENZENE 
Synthesis and Crystal Structure of [(ArO)_2(THF)Sm(μ-OH)]_2·2THF(Ar=C_6H_(2-)~tBu_3-2,4,6)
《Chinese Journal of Structural Chemistry》2005年第7期741-744,735,共5页YUANFu-Gen GONGJing 
The project was supported by the Qinglan Foundation of Jiangsu Province (HB2001-27)the Foundation of Educational Ministry of Jiangsu Province (04KJD560171)
The title complex [(ArO)2(THF)Sm(μ-OH)]2?2THF (Ar = C6H2-tBu3-2,4,6) was obtained by the hydrolysis of divalent (ArO)2Sm(THF)3?THF in toluene. It crystallizes in monoclinic, space group P21/c with a = 14.7968(14), b ...
关键词：DIVALENT SAMARIUM ARYLOXIDE LANTHANIDE 
Reactivity and structural characterization of divalent samarium aryloxide with diethylaluminum chloride
《Chinese Science Bulletin》2003年第20期2164-2167,共4页YAOYingming QIGuizhong SHENQi HUJingyu LINYonghua 
supported by the National Natural Science Foundation of China(Grant No.20072027).
Reaction of (ArO)2Sm(THF)4 (ArO = 2,6-di- tert-butyl-4-methylphenolate) with Et2AlCl in THF gives SmCl2 (1) and (ArO)AlEt2(THF) (2) via ligand exchange. Complex 1 reacts with cyclooctatetraene (C8H8) to give [(C8H8)Sm...
关键词：二氯化钐 氯化二乙基铝 反应性能 结构特征 晶体结构 
Synthesis and Crystal Structure of [(ArO)_2Sm-(OPPh_3)(μ-OH)]_2(ArO = 2,6-~tBu-4-Me-C_6H_2O)
《Chinese Journal of Structural Chemistry》2003年第2期143-146,共4页姚英明 张可达 喻龙宝 沈琪 雷玉叶 孙杰 
Financially supported by NNSFC (20072027); the Education Department of Jiangsu province and the Key Laboratory of Organic Synthesis of Jiangsu province
The title complex, [(ArO)2Sm(OPPh3)(m-OH)]2 (ArO = 2,6-tBu2-4-Me-C6H2O), was obtained by the hydrolysis reaction of divalent samarium aryloxide, Sm(ArO)2(THF)4, in the presence of triphenylphosphine oxide (OPPh3) in t...
关键词：LANTHANIDE SAMARIUM ARYLOXIDE crystal structure 
Synthesis and crystal structures of bis(cyclopentyl)gallium phenoxide dimer and bis (cyclopentyl) gallium naphthoxide dimer
《Chinese Journal of Chemistry》1994年第6期542-548,共7页HAN, Ying TAO, Wen-Tian HUANG, Yao-Zeng JIN, Xiang-Lin SUN, JieLaboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China 
Project supported by the National Natural Science Foundation of China and Chinese Academy of Sciences.
Tricyclopentylgallium reacted with phenol, naphthol respectively to yield phenox-ide (or naphthoxide) of biscyclopentylgallium which have been characterized by elemental analysis, IR, 1H NMR and mass spectrometry. X-...
关键词：Crystal structure bis(cyclopentyl)gallium aryloxide dimer. 
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