supported by the National Natural Science Foundation of China(Nos.22425107,92461303,22371140,and 92161102(Z.-M.S.))and(No.22301143(L.Q.)).
The reactions of K_(5)Pn_(4)(Pn=Sb and Bi)and CpRh(PPh_(3))_(2)(Cp=C_(5)H_(5),cyclopentadiene)in ethylenediamine(en)solutions resulted in a series of new Pn_(7)^(3−)−adducts,{Pn_(8)[Rh(PPh_(3))]_(2)}^(2−),{Sb_(7)[Rh(P...
support by the National Natural Science Foundation of China(Nos.51871133 and 51901108);the support of the Taishan Scholar Foundation of Shandong Province,the Key Research and Development Program of Shandong Province(No.2021ZLGX01);the program of Jinan Science and Technology Bureau(No.2019GXRC001)。
Highly active and stable electrocatalysts to produce hydrogen through water splitting are crucial for clean energy systems but are still challenging.Herein,a novel self-templating strategy was proposed to synthesize o...
supported by the National Natural Science Foundation of China(No.51872292);the young project of Anhui Provincial Natural Science Foundation(No.1908085QB83).
Here we report a vapor-phase reaction approach to fabricate rhodium(I)-dodecanethiol complex coated on carbon fiber cloth(Rh(I)-SC_(12)H_(25)/CFC),followed by low-temperature pyrolysis to achieve dodecanethiol modifie...
Striking effects are expected in solid-solution alloying,which offers enormous possibilities for various applications,especially in industrial catalysis.However,phase diagrams have revealed that a wide range of metall...
supported by the National Science Foundation (CHE-1565657);the Army Research Office (Award W911NF- 15-1-0320);supported by the Department of Defense (DoD) through the National Defense Science & Engineering Graduate Fellowship (NDSEG) Program.
In some cases, illumination of traditional thermal catalysts and tailored plasmonic photocatalysts may synergistically combine thermal and nonthermal mechanisms to enhance reaction rates and improve product selectivit...
supported by the National Key R&D Program of China (Nos.2016YFA0202801 and 2017YFA0700101);the National Natural Science Foundation of China (Nos.21573119,21590792,21890383,and 21872076);China Postdoctoral Science Foundation (No.2018M631444).
Bimetallic nanocrystals (BMNCs) with distinguished electronic and chemical properties from those of their parent metals,offer the opportunity to obtain new catalysts with enhanced selectivity,activity,and stability.He...
Direct methanol fuel cells (DMFCs) have received tremendous research interests because of the facile storage of liquid methanol vs.hydrogen.However,the DMFC today is severely plagued by the poor kinetics and rather hi...
This work was financially supported by the National Key Research and Development Program of China (No. 2017YFA0208300), the National Natural Science Foundation of China (Nos. 11505187, 11404314, 11422547, 21471143, and 51676178) and the Fundamental Research Funds for the Central Universities (Nos. WK2310000066, WK2310000050, WK2340000076, and KY2310000019), and Youth Innovation Promotion Association CAS (Nos. CX2310000054 and CX2310000091). We also thank the beamline 1W1B at the Beijing Synchrotron Radiation Facility and the Beamline BL14W1 at Sh~anghai Synchrotron Radiation Facility for help in characterizations.
Designing active sites and engineering electronic properties of heterogeneous catalysts are both promising strategies that can be employed to enhance the catalytic activity for CO2 hydrogenation. Herein, we report RhC...
Cyclic penta-twinned noble metal nanocrystals exhibit promising properties due to their unique geometric and electronic structures. However, the controlled synthesis of cyclic penta-twinned nanostructures, especially ...
This work was supported by National Natural Science Foundation of China (No. 21473111), Natural Science Foundation of Shaanxi Province (No. 2015JM2043),and Fundamental Research Funds for the Central Universities (Nos. GK201602002 and GK201503037).
Nanocrystals of Rh, an important member of the noble metal catalyst family, have wide applications in heterogeneous catalytic reactions. Controlling the morphology of these noble metal nanocrystals has become an effec...