ELECTROSYNTHESIS

作品数:126被引量:170H指数:7
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相关作者:徐瑞东陈步明郭忠诚刘强胡钢更多>>
相关机构:昆明理工大学中国科学院过程工程研究所南阳师范学院北京工业大学更多>>
相关期刊:《Journal of Rare Earths》《Nano Research Energy》《Nano-Micro Letters》《Science China Chemistry》更多>>
相关基金:国家自然科学基金天津市自然科学基金中国博士后科学基金国家重点基础研究发展计划更多>>
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Ultrathin nickel sulfide nanosheets for sulfur ion electrooxidation assisted acetonitrile electroreduction
《Science China Chemistry》2025年第3期951-960,共10页Xiao-Hui Wang Ze-Nong Zhang Na Li Xuan Ai Xue Xiao Yu Chen Shu-Ni Li 
supported by the National Natural Science Foundation of China (22309108);the Science and Technology Innovation Team of Shaanxi Province (2023-CX-TD-27);the Fundamental Research Funds for the Central Universities (GK202202001);Sanqin Scholars Innovation Teams in Shaanxi Province,China。
Electrochemical reduction of acetonitrile(ACN)to ethylamine(ETA)is a new strategy for producing high-value chemicals.Herein,the ultrathin nickel sulfide nanosheets(Ni_(x)S_(y)NSs)anchored on nickel foam(NF)nanohybrid(...
关键词:ELECTROSYNTHESIS hydrogenation two-dimensional nanomaterials acetonitrile reduction reaction sulfur ion oxidation reaction 
Confluence of asymmetric catalysis and electrosynthesis in sustainable chemical transformations
《Science China Chemistry》2024年第3期755-758,共4页Qinglin Zhang Kang Liang Chang Guo 
supported by the National Natural Science Foundation of China(21971227,22222113);CAS Project for Young Scientists in Basic Research(YSBR-054);the Fundamental Research Funds for the Central Universities(WK9990000090,WK9990000111);the Chinese Postdoctoral Science Foundation(2022TQ0324,2023M733376)。
Electrosynthesis has gained widespread recognition for its extraordinary ability to precisely control the redox process.This outstanding capability enables the direct conversion of non-functionalized substrates into r...
关键词:Confluence of asymmetric catalysis and electrosynthesis in sustainable chemical transformations 
Electrochemical radical-polar crossover:a radical approach to polar chemistry被引量:1
《Science China Chemistry》2024年第2期450-470,共21页Zhoumei Tan Haonan Zhang Kun Xu Chengchu Zeng 
supported by the National Natural Science Foundation of China (22171015,22271009);the Beijing Natural Science Foundation (2222003);the Beijing Municipal Education Committee Project (KZ202110005003,KM202110005006)。
Radical-polar crossover(RPC) reaction bridges the gap between one-and two-electron reactivities,thus providing an ideal solution to overcome the limitations of both radical and polar chemistry.In this manifold,organic...
关键词:ELECTROSYNTHESIS radical-polar crossover radical chemistry polar chemistry alkene functionalization 
Efficient ammonia electrosynthesis from nitrate via a three-step relay mechanism
《Science China Chemistry》2024年第1期319-320,共2页Haifeng Jiang Gao-Feng Chen Haihui Wang 
Electrocatalytically converting nitrate waste to value-added ammonia(NO3−RR)is beneficial to environmental restoration and an attractive candidate for green ammonia production[1].However,developing NO_(3)^(-)RR in an ...
关键词:AMMONIA NITRATE KINETICS 
Electrosynthesis of hydroxylamine from nitrate reduction in water
《Science China Chemistry》2023年第6期1758-1762,共5页Xianen Lan Chuanqi Cheng Chengying Guo Minghao Guo Tieliang Li Yongmeng Wu Yifu Yu Bin Zhang 
supported by the National Natural Science Foundation of China(22271213(B.Z.)and 22071173(Y.Y.));the Haihe Laboratory of Sustainable Chemical Transformations;the National Postdoctoral Science Foundation of China(2022M722357(Y.W.))。
Hydroxylamine(NH_(2)OH),a vital but unstable industrial feedstock,is presently prepared under harsh conditions that cause environmental and energy concerns.Here,we report an electrochemical method to prepare oximes,wh...
关键词:ELECTROSYNTHESIS HYDROXYLAMINE nitrate reduction amorphous Mn reaction pathway 
Electrosynthesis of ^(15)N-labeled amino acids from ^(15)N-nitrite and ketonic acids被引量:1
《Science China Chemistry》2023年第6期1854-1859,共6页Yongmeng Wu Mengyang Li Tieliang Li Jinghui Zhao Ziyang Song Bin Zhang 
supported by the National Natural Science Foundation of China(22271213);the National Postdoctoral Science Foundation of China(2022M722357)。
^(15)N isotope-labeled amino acids(^(15)N-amino acids)are crucial in the fields of biology,medicine,and chemistry.^(15)N-amino acids are conventionally synthesized through microbial fermentation and chemical reductive...
关键词:green synthesis ^(15)N-labeled amino acids ELECTROSYNTHESIS C-N bond isotope labeling 
Defect engineering for advanced electrocatalytic conversion of nitrogen-containing molecules被引量:4
《Science China Chemistry》2023年第4期1052-1072,共21页Dongdong Wang Chen Chen Shuangyin Wang 
supported by the National Key R&D Program of China(2020YFA0710000);the National Natural Science Foundation of China(21825201 and 22102054)。
Electrocatalytic conversion of nitrogen-containing molecules into valuable chemicals is a promising strategy to alleviate anthropogenic imbalances in the global nitrogen cycle,but developing efficient electrocatalysts...
关键词:defect engineering ELECTROCATALYSIS nitrogen-containing molecules C-N bond ELECTROSYNTHESIS 
Recent advances in electrooxidative radical transformations of alkynes被引量:3
《Science China Chemistry》2023年第3期703-724,共22页Yan Zhang Zhenzhi Cai Svenja Warratz Chanchan Ma Lutz Ackermann 
supported by the Natural Science Foundation of Zhejiang Province(LY22B020001);the National Natural Science Foundation of China(21702188);the ERC Advanced Grant(101021358);the Gottfried-Wilhelm-Leibniz award to LA(DFG).
During the past few years,electrochemical oxidative reactions through radical intermediates have emerged as an environmentally-benign,powerful platform for the facile formation of C–E(E=C,N,S,Se,O and Hal)bonds throu...
关键词:ELECTROSYNTHESIS ELECTROOXIDATION RADICALS ALKYNES ADDITIONS difunctionalization 
Wide-pH-range adaptable ammonia electrosynthesis from nitrate on Cu-Pd interfaces被引量:3
《Science China Chemistry》2023年第3期913-922,共10页Yongtao Wang Peng Zhang Xiaoyun Lin Gong Zhang Hui Gao Qingzhen Wang Zhi-Jian Zhao Tuo Wang Jinlong Gong 
supported by the National Key R&D Program of China(2021YFA1500804);the National Natural Science Foundation of China(22121004,51861125104);the Natural Science Foundation of Tianjin City(18JCJQJC47500);Haihe Laboratory of Sustainable Chemical Transformations,the Program of Introducing Talents of Discipline to Universities(BP0618007)and the Xplorer Prize.
Ammonia production via electrochemical nitrate reduction is essential for environmental protection and the emerging hydrogen economy. Complex nitrate wastewater with a wide pH range calls for flexible catalysts with h...
关键词:nitrate reduction ammonia synthesis Cu-Pd interfaces reaction kinetics break p H limitation 
A nickel-iron layered double hydroxide-supported Au catalyst for efficient electrocatalytic C-C coupling reaction coupled with H_(2) production被引量:1
《Science China Chemistry》2022年第11期2307-2317,共11页Meng Jin Lina Ma Lina Zhou Kaiyue Ji Xiaomeng Xue Bi-Jie Li Haohong Duan 
the National Natural Science Foundation of China(21978147,21935001,22090030,22105015);State Key Laboratory of Catalytic Materials and Reaction Engineering(RIPP,SINOPEC)。
Coupling of cathodic H_(2) production with electrosynthesis of organic compounds not only solves the problem of sluggish oxygen evolution reaction(OER) kinetics, but also produces valuable chemicals. However, this str...
关键词:layered double hydroxide ELECTROSYNTHESIS OER-substituted reaction H_(2)production C-C coupling 
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