TRICHLOROSILANE

作品数：16被引量：10H指数：1
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Asymmetric Synthesis of Novel Axially Chiral 2,2＇-Bipyridine N,N＇-Dioxides Bearing α-Amino Acid Residues and Their Applications in Enantioselective Allylation of Aromatic Aldehydes with Allyltrichlorosilane被引量：1
《Chinese Journal of Chemistry》2013年第4期485-493,共9页Hongwu Zhao Yuanyuan Yue Hailong Li Zhihui Sheng Zhao Yang Wei Meng 
We thank Beijing Municipal Commission of Edu- cation （No. JC015001200902）, Beijing Municipal Natu- ral Science Foundation （Nos. 710201, 2122008）, Basic Research Foundation of Beijing University of Technol- ogy （X40 15001201101）, Funding Project for Academic Human Resources Development in Institutions ofHigher Learning Under the Jurisdiction of Beijing Municipality （No. PHR201008025）, Doctoral Scientific Research Start-up Foundation of Beijing University of Technology （No. 52015001200701） for financial sup- ports.
A series of novel axially chiral 2,2＇-bipyridine N,N＇-dioxides bearing C1 or C2-symmetry have been synthesized by the use of enantiopure a-amino acids as chiral sources. The absolute stereochemistry of the axial chi...
关键词：2 2＇-bipyridine N N＇-dioxide organocatalyst asymmetric catalysis enantioselective allylation allyl-trichlorosilane 
Formation of Chiral a-Monofluorinated-.8-amino Esters through Organocatalytic Asymmetric Reduction of a-Fluoro-j3-enamino Esters by Trichlorosilane
《Chinese Journal of Chemistry》2012年第11期2636-2640,共5页张鹏 王超 周莉 孙健 
Acknowledgement We are grateful for financial supports from the Na- tional Natural Science Foundation of China （Project Nos. 20972151, 21272227 and 91013006）.
A concise method was developed to prepare chiral a-monofluorinated-β-amino esters through N-sulfinyl urea catalyzed asymmetric hydrosilylation of a-fluoro-β-enamino esters, which affords high yields, good to high di...
关键词：asymmetric reduction sulfinyl urea a-fluorinated-β-amino ester STEREOSELECTIVITY 
Ab initio Calculation and Kinetic Study for the Abstraction Reaction of H with SiHCl_3
《Chinese Journal of Chemistry》2002年第3期214-219,共6页张庆竹 王少坤 顾月姝 
ProjectsupportedbytheResearchFundfortheDoctoralProgramoftheMinistryofEducationofChina (No .19990 42 2 0 1)
The mechanism of the reaction of H with SiHCl_3 has been investigated at highlevel of ab initio molecular orbital theory. Theoretical analysis provides a conclusive evidencethat the main process occurring in this reac...
关键词：TRICHLOROSILANE abstraction reaction variational transition state 
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