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support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).
Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical ...
Financial supports from the NSFC(No.21633013);the Cooperation Foundation of Dalian National Laboratory for Clean Energy of CAS(No.DNL201901);the"Light of West China"Program,Fujian Innovation Academy,Key Research Program of Frontier Sciences(No.Q.YZDJ-SSW-SLH051);Strategic Priority Research Program(No.XDA21020700)of the CAS are gratefully acknowledged.
Summary of main observation and conclusion An efficient and organic ligand-free heterogeneous catalytic system for hydroformylation of olefins is highly desirable for both academy and industry.In this study,simple Rh ...
Supported by the Ministry of Science and Technology of China(No.2009CB623503)
A phosphite ligand modified heterogeneous catalyst was developed for the hydroformylation of internal olefins to linear aldehydes, which showed a high activity and high regioselectivity and could be separated easily b...
supported by the National Key Fundamental Research Development Plan("973"Plan,No.2009CB623503)
A phosphite ligand modified Rh/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration...
A novel TPPTS-Rh/SiO2 catalyst, prepared by directly modifying a heterogeneous high-surface-area Rh/SiO2 catalyst with water-soluble TPPTS ligands, could decrease the resistance of mass transfer in water/oil biphasic ...
The project is supported by National Natural Science Foundation of China
The polymer-supported cluster FeCo3 (CO)_(12) (μ3-AuPph_2 CH_2) (4) has been synthesized through reaction of CH_2 ph_2 PAuCl with the cluster anion FeCo_3 (CO)_(12)^-. They are characterized through IR spectra, elect...