The authors gratefully acknowledge financial support from National Key R&D Program of China(2019YFC1905300);National Natural Science Foundation of China(No.22268019);Hunan Provincial Natural Science Foundation of China(No.2021JJ40436)。
Acetalization represents an appealing approach for the valorization of biobased platform molecules into valuable chemicals and fuels.Typically,it serves as both a synthesis tool for renewable cyclic acetals and a prot...
In this work,we have reported the synthesis of a series of heterogeneous catalysts,viz.,[HMIm]_(3)[PW_(12)O_(40)]@MOF-Fe,[HMIm]_(3)[PMo_(12)O_(40)]@MOF-Fe,and[HMIm]_(4)[SiW_(12)O_(40)]@MOFFe,by a simple impregnation m...
National Natural Science Foundation of China(Grant Nos.22250410258 and 22250410259);the Ministry of Science and Technology of the People's Republic of China for financial support.
The structures assigned to all four members,1-4,of the recently reported favolasin class of natural product have been prepared for the first time by chemical synthesis.Suzuki-Miyaura cross-coupling chemistry was used ...
the National Natural Science Foundation of China(No.21701110,T.L.);Solvay China(T.L.,V.O.,Y.Y.);and the start-up funding from ShanghaiTech University(T.L.).This work made use of the resources of the Instrum ental Analysis Center of SPST at ShanghaiTech University.This work is partially supported by CfiEM of SPST at ShanghaiTech(No.EM02161943).
The aerobic oxidation of monoalcohols and diols to acetals is an important academic and industrial challenge for the production of fine chemicals and intermediates.The existing methods usually rely on a two-step proce...
the financial support from Ministry of Science and Technology of China(Grant No.2016YFA0202804);the National Natural Science Foundation of China(Grant Nos.21872052,21533002,21571128 and 21603075).
Hierarchical core/shell Zeolite Socony Mobil-five(ZSM-5)zeolite was hydrothermally postsythesized in the solution of NaOH and diammonium surfactant via a dissolution-reassembly strategy.The silica and alumina species ...
financially supported by the National Natural Science Foundation of China(Nos.21673077,21473058,and 21273077)
The phosphine-functionalized phosphonium-based ionic liquids(dppm-Q, dppe-Q, dppp-Q and dppb-Q) as the bi-functional ligands enable the efficient one-pot tandem hydroformylationeacetalization. It was found that, in dp...
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant No. 21576243) and the Public Project of Zhejiang Province of China (2016C37057).
Abstract Heterogeneous catalysts with convenient recyclability and reusability are vitally important to reduce the cost of catalysts as well as to avoid complex separation and recovery operations. In this regard, magn...
supported by the Talent Introduction Fund of Yangzhou University, Jiangsu Social Development Project(No. BE2014613);Six Talent Peaks of Jiangsu Province (No. 2014-XCL-013);the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
Polyvinyl butyral(PVB) polymer was successfully synthesized using ionic liquid(IL) catalyst. The synthesis of PVB was achieved by acetalization of polyvinyl alcohol(PVA) and butyraldehyde(BA) in the presence o...
Supported by the Chinese National General Administration of Quality Supervision,Inspection and Quarantine(2012IK048,2011IK041);the National Natural Science Foundation of China(21103111)
The novel solid acid with both sulfonic and carbonyl acid groups has been synthesized from 3-((2-sulfoethoxy) carbonyl)acrylic acid and tetraethyl orthosilicate(TEOS). The catalytic activities were investigated throug...
This paper reports a practical and green method for the acetalization of carbonyl compounds as pentaerythritol diacetals and diketals derivatives using cellulose sulfuric acid as a biodegradable and reusable solid aci...