The kinetics of reaction between cyclic monoimides (succinimide, phtalimide, and glutarimide) with ethylene and propylene oxides in presence of sodium hydroxide was studied. The effect of substrate and catalyst concen...
Direct photolysis and quenching experiments with styrene oxide support the existence of an efficient triplet photochemical pathway to benzyl radical formation. Similar photolytic behavior for styrene glycol carbonate ...
Literature describes kinetics of reactions of alcohols, phenols, carboxylic acids, amines and amides with oxiranes such as ethylene oxide and propylene oxide. However, there is no information regarding kinetic of reac...
The mechanism of reaction of cyclic monoimides with oxiranes was established based upon kinetic studies and product analysis. It has been established that the reaction proceeds through initial formation of an adduct o...
An efficient synthesis of alkyl bis(dimethylamino)methylenecarbamodithioates via a one-pot reaction between 1,1,3,3- tetramethylguanidine, carbon disulfide and substituted oxiranes, in good yields, is described.
An efficient synthesis of 1,3-oxathiolane-2-imin derivatives is described via one-pot reaction between arylisothiocyanats, asymmetrically substituted oxiranes and catalytic amount of methanol.The mild reaction conditi...
A ferrocenylsulfides 1-2 mediated sulfur ylide epoxidation reaction was found to stereoselectively afford trans-oxiranes in excellent yields with recoverable starting material.