the financial support for this investigation from the National Natural Science Foundation of China(No.22072111;the Fundamental Research Funds for the Central Universities(No.2023IVA055).
Nucleophilic phosphine and amine catalyst-switched chemodivergent[4+1]and[3+3]annulations of allenyl imides andβ,γ-enones have been developed,furnishing highly substituted 2-cyclopentenone and 2-pyranone derivatives...
supported by the Fundamental Research Funds for the Central Universities,China(No.buctrc202103);the National Natural Science Foundation of China(Nos.21975263,22171019);the Project of the SINOPEC(No.222131);the Open Project Programs of Wuhan National Laboratory for Optoelectronics,China(No.2021WNLOKF005);the Fund of the State Key Laboratory of Fine Chemicals(Dalian University of Technology),China(No.KF2201);the Fund of the State Key Laboratory of Optoelectronic Materials and Technologies(Sun Yat-sen University),China.
Aromatic six-membered imides suffer the introduction of bulky substituents at the imide positions due to the formation of isoimides and low reactivity,preventing from the investigation of the intrinsic molecular prope...
supported by the National Natural Science Foundation of China(22122503,22235005,and 22275112);the Shandong Provincial Natural Science Foundation(ZR2019ZD50)。
Unraveling the key structural features to maximize the chiroptical properties is of significance for developing high-performance chiral materials.Here we present our first attempt to elucidate and understand the molec...
Polyimides are well-known for their high chemical inertness and thermal stability. However, it is usually challenging to synthesize UV-curable polyimides since the imidization reaction requires such harsh conditions t...
National Natural Science Foundation of China (Grant Nos. 21633011, 21603220 and 21872137);Sino-Japanese Research Cooperative Program of Ministry of Science and Technology (2016YFE0118300);DICP (DICP DMT0201504);Youth Innovation Promotion Association CAS (No. 2018213);Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM).
What is the most favorite and original chemistry developed in your research group? Developments of alkali/alkaline earth amides, imides and hydrides for hydrogen storage and for catalytic ammonia synthesis are the mos...
The kinetics of reaction between cyclic monoimides (succinimide, phtalimide, and glutarimide) with ethylene and propylene oxides in presence of sodium hydroxide was studied. The effect of substrate and catalyst concen...
The novel 1,2-diaryl substituted pyrrolo[3,4-b]pyridine-5,7-diones were selectively synthesized in high yields by the base catalyzed cyclization reaction of 3-arylamino-l-methyl-lH-pyrrole-2,5-diones with cinnamaldehy...
Financial support from Tongji University(20123231)is gratefully acknowledged.
A new protocol for the synthesis of imides has been developed. In the presence of copper catalyst, N-benzylamideswere oxidized to the corresponding imides by TBHP/TEMPO system in moderate to good yields.
Literature describes kinetics of reactions of alcohols, phenols, carboxylic acids, amines and amides with oxiranes such as ethylene oxide and propylene oxide. However, there is no information regarding kinetic of reac...
The mechanism of reaction of cyclic monoimides with oxiranes was established based upon kinetic studies and product analysis. It has been established that the reaction proceeds through initial formation of an adduct o...