EPIMERIZATION

作品数：7被引量：9H指数：2
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Indole methylation protects diketopiperazine configuration in the maremycin biosynthetic pathway被引量：3
《Science China Chemistry》2016年第9期1224-1228,共5页Yingxia Lan Yi Zou Tingting Huang Xiaozheng Wang Nelson L. Brock Zixin Deng Shuangjun Lin 
supported by the National Natural Science Foundation of China (NNSFC, 31425001 and 31070057 for SL);the Leopoldina Fellowship Program (German National Academy of Sciences Leopoldina, LPDS 2013-12 for NLB)
The maremycin biosynthetic gene cluster has been identified in Streptomyces sp. B9173. Comparative metabolic profiling with knockout mutant strains led to the identification of new products correlated to the maremycin...
关键词：BIOSYNTHESIS maremycin N-METHYLATION METHYLTRANSFERASE EPIMERIZATION 
Two remarkable epimerizations imperative for the success of an asymmetric total synthesis of (+)-aigialospirol
《Science China Chemistry》2011年第1期31-42,共12页FIGUEROA Ruth FELTENBERGER John B. GUEVARRA Christle C. HSUNG Richard P. 
PRF-AC(42106) for support and Dr.Victor Young and Ben Kucera(University of Minnesota) for X-ray analysis.CCG thanks UW for an NIH-CBI Training Grant
Two remarkable epimerization processes were uncovered during our pursuit of an enantioselective synthesis of(+)-aigialospirol featuring a cyclic acetal tethered ring-closing metathesis.Through modeling,we were able to...
关键词：cyclic acetal tethered RCM （＋）-aigialospirol anomeric effect and epimerization. 
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