Lithium amides have been proved to be effective anionic initiators for the anionic polymerization of acrylonitrile to get high molecular weight polyacrylonitrile in this study. Polyacrylonitrile with weightaverage mol...
Financial support of this work is provided by National Natural Science Foundation of China(No.51373027);Education Department of General Item of China(No.LR2012017)
A novel poly(styrene-co-acrylonitrile)-graft-polyethylene glycol (SAN-g-PEG) copolymer was synthesized as new solid-solid phase change materials (SSPCMs) by grafting PEG to the main chain of poly(styrene-co-acr...
Financial support of this work from Important National Research Program‘‘863’’(No.2012AA030313-1);Undergraduate Innovation Project(No.1065210232130740);The Fundamental Research Funds for the Central Universities(No.JUSRP11450)
In order to improve the stabilization and spinnability of polyacrylonitrile, a bifunctional comonomer containing both ester and amide groups was synthesized to prepare poly(acrylonitrile-co-3- aminocarbonyl-3-butenoi...
supported by the National Natural Science Foundation of China(Nos.51073031, 20971021 and 20974018);Doctoral Dissertation Innovation Project(No.BC201004)
A novel bifunctional comonomer 3-ammoniumcarboxylate-butenoic acid-methyl ester (ACBM) was synthesized tor preparing poly[acrylonitrile-co-(3-ammoniumcarboxylate-butenoic acid-methyl ester)] [P(AN-co-ACBM)] copo...
Polyacrylonitrile-block-poly(methyl acrylate)(P(AN-b-MA)) was synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization employing macro-RAFT agent (PAN-RAFT) as the chain transfer...
Acrylonitrile reacts with aryl iodides in the presence of tri-n-butylamine and a catalytic amount of a silica-bound arsine palladium(0) complex to afford stereoselectively (E)-cinnamo- nitriles in high yields.
the National Natural Science Foundation of China for financial support (Grant no. 20074033).
In this work, a novel sugar-containing copolymer was synthesized by the copolymerization of a-allyl glucoside (AG) with acrylonitrile (AN). The copolymers were characterized by NMR spectroscopy. It was found that ac...
This work was supported by the Natural Science Foundation of Jiangxi Province.
Arylation of acrylamide and acrylonitrile were carried out with various arenediazonium tetrafluoroborates in the presence of a catalytic amount of Pd(OAc)(2) in ethanol and a variety of substituted (E)-cinnamamides an...