CYCLOPROPANE

作品数：51被引量：33H指数：3
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相关领域：理学更多>>
相关作者：李中军孟祥豹李庆李云锋更多>>
相关机构：北京大学更多>>
相关期刊：《中国生物学文摘》《Chinese Journal of Natural Medicines》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划天津市自然科学基金中国博士后科学基金更多>>
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Synergy of activating substrate and introducing C–H…O interaction to achieve Rh2(II)-catalyzed asymmetric cycloisomerization of 1,n-enynes
《Science China Chemistry》2020年第9期1230-1239,共10页Rui Wu Kai Chen Jun Ma Zhi-Xiang Yu Shifa Zhu 
the National Natural Science Foundation of China(21871096;21672071;91856105);the Ministry of Science and Technology of China(2016YFA0602900);the Natural Science Foundation of Guangdong(2018B030308007;2018A030310359;2016A030310433);the Science and Technology Program of Guangzhou(201707010316);the Fundamental Research Funds for the Central Universities;South China University of Technology。
We report the first Rh2(II)-catalyzed asymmetric cycloisomerization of activated enynes to provide cyclopropane-fused tetrahydropyridines in good yields and excellent enantioselectivities under mild conditions.The act...
关键词：asymmetric cycloisomerization chiral cyclopropane dirhodium catalysis CARBENE 
Attractive natural products with strained cyclopropane and/or cyclobutane ring systems被引量：6
《Science China Chemistry》2016年第9期1126-1141,共16页Yao-Yue Fan Xin-Hua Gao Jian-Min Yue 
supported by the National Natural Science Foundation of China (21532007)
The strained cyclopropane and/or cyclobutane subunits occurred in many complex natural products including terpenoids, steroids and alkaloids. Natural products with cyclopropane and/or cyclobutane motifs not only furni...
关键词：natural products cyclopropane-containing cyclobutane-containing biological activity biosynthetic pathway 
Synthesis of spiro-cyclopropane derivatives containing multiple chiral centers被引量：3
《Science China Chemistry》1999年第3期268-276,共9页黄慧 陈庆华 
Project supported by the National Natural Science Foundation of China (Grant No. 29672004)
Tandem asymmetric double Michael addition/internal nucleophilic substitution of the novel chiral source, 5-(l-menthyloxy)-3-bromo-2(5H)-furanone with nucleophilic alcohol compounds has been investigated. The tandem as...
关键词：5-( l-menthyloxy)-3-bromo-2(5H)-furanone tandem reaction asymmetric double Michael addition /internal NUCLEOPHILIC SUBSTITUTION crystal structure spiro-cyclopropane derivatives with MULTIPLE chiral centers. 
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