NUCLEOPHILIC

作品数:66被引量:46H指数:3
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相关领域:理学更多>>
相关机构:大连理工大学华东理工大学更多>>
相关期刊:《Green Energy & Environment》《Open Journal of Physical Chemistry》《Nano-Micro Letters》《Science China Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry天津市自然科学基金更多>>
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Amphipathic Phenylalanine-Induced Nucleophilic-Hydrophobic Interface Toward Highly Reversible Zn Anode被引量:1
《Nano-Micro Letters》2024年第9期95-109,共15页Anbin Zhou Huirong Wang Fengling Zhang Xin Hu Zhihang Song Yi Chen Yongxin Huang Yanhua Cui Yixiu Cui Li Li Feng Wu Renjie Chen 
supported by the Joint Funds of the National Natural Science Foundation of China(U2130204);the National Natural Science Foundation of China(52002022);the Young Elite Scientists Sponsorship Program by CAST(YESS20200364);the Beijing Outstanding Young Scientists Program(BJJWZYJH01201910007023).
Aqueous Zn^(2+)-ion batteries(AZIBs),recognized for their high security,reliability,and cost efficiency,have garnered considerable attention.However,the prevalent issues of dendrite growth and parasitic reactions at t...
关键词:Zn anode PHENYLALANINE Adsorption energy Solvation sheath 
A non-nucleophilic electrolyte based on all-inorganic salts with conditioning-free characteristic for rechargeable magnesium batteries
《Journal of Magnesium and Alloys》2024年第8期3357-3369,共13页Jiaxin Wen Jingdong Yang Xueting Huang Xin Zhang Guangsheng Huang Jingfeng Wang Lingjie Li Fusheng Pan 
supported by the Science and Technology Research Program of Chongqing Municipal Education Commission(Grant No.KJQN 202103202);the Doctoral Research Foundation of Chongqing Industry Polytechnic College(Grant No.2022GZYBSZK2-11).
Conditioning-free electrolytes with high reversibility of Mg plating/stripping are of vital importance for the commercialization of the superior rechargeable magnesium batteries(RMBs).In the present work,a non-nucleop...
关键词:Rechargeable magnesium batteries Non-nucleophilic electrolyte All-inorganic salt Conditioning-free Mg plating/stripping 
Nucleophilic amino acids as a renewable alternative to petrochemically-derived amines in glycerol epoxy resins
《Journal of Bioresources and Bioproducts》2024年第2期222-232,共11页Yunyi Liang Yonghong Luo Yingji Wu Xiaona Li Quyet Van Le Jianzhang Li Changlei Xia 
funded by the National Key R&D Program of China(No.2022YFD2200105).
The standard epoxy resin curing agents revealed are from unsustainable petroleum-based sources,which produce poisonous exhaust when cured.Amino acids,a bio-based epoxy curing agent with amino and carboxyl groups,are a...
关键词:Curing agent Amino acids Bio-based epoxy resins LYSINE Glutamic acid 
Chemodivergent annulations of allenyl imides andβ,γ-enones switched by nucleophilic phosphine and amine catalysts
《Chinese Chemical Letters》2024年第1期254-258,共5页Bingsen Xiang Yuhao Wang Chuqing Xiao Fengkai He Yiyong Huang 
the financial support for this investigation from the National Natural Science Foundation of China(No.22072111;the Fundamental Research Funds for the Central Universities(No.2023IVA055).
Nucleophilic phosphine and amine catalyst-switched chemodivergent[4+1]and[3+3]annulations of allenyl imides andβ,γ-enones have been developed,furnishing highly substituted 2-cyclopentenone and 2-pyranone derivatives...
关键词:Chemodivergent Nucleophilic catalysis ALLENE CYCLOPENTENONE Pyranone 
Recent advances in annulations enabled by nucleophilic Lewis base/metal dual catalysis
《Chinese Chemical Letters》2023年第10期12-26,共15页Qian Wang Yinggao Meng Lulu Wu Er-Qing Li 
the National Natural Science Foundation of China(No.21702189);the Key Scientific and Technological Project of Henan Province(No.202102310004);Science and Technology Research and Development Plan Joint Fund(cultivation of superior disciplines)Project(No.222301420042);Zhengzhou University(No.JC21253007)of China for financial support of this research.
Metal/nucleophilic Lewis base dual catalysis has been recognized as a reliable and promising strategy for finishing ideal organic synthesis over the past decades.The new strategy can usually achieve some chemical reac...
关键词:Lewis base Metal catalysis Annualtion Dual catalysis Synthetic methods 
Design and Synthesis of Multi-Functional Polymeric Binders for High-Performance Lithium-Sulfur Batteries Based on Ring Opening Polymerization of Thiolactone
《Chinese Journal of Chemistry》2023年第20期2619-2627,共9页Yuqing Zhao Shiqun Geng Gaojie Yan Xiongwei Qu Haifeng Ji Yi Feng Xiaojie Zhang 
This work was supported by the National Natural Science Foundation of China(Project No.U20A20260);the China Central Government Guide for the Development of Local Science and Technology Special Funds(226Z1202G);the Natural Science Foundation of Hebei Province(Grant Nos.B2020202042,B2020202073 and C20200320).
The application of high-performance lithium-sulfur(Li-S)batteries is severely influenced by the“shuttle effect”of polysulfides and the volume change of sulfur cathode.Herein,two different polymeric binders SOT-A and...
关键词:Li-S batteries Polymeric binders Nucleophilic ring-opening polymerization Polar groups Three-dimensional network 
Development and Application of Trifluoromethoxylating Reagents被引量:2
《Chinese Journal of Chemistry》2023年第17期2179-2196,共18页Yafeng Si Pingping Tang 
supported by the National Key Research and Development Program of China(2021YFF0701700);NFSC(21925105,92156001);the Natural Science Foundation of Tianjin(Grant No.18JCJQJC47000);NCC Fund(NCC2020FH07);the Haihe Laboratory of Sustainable Chemical Transformations,and the Fundamental Research Funds for the Central Universities.
Comprehensive Summary,The trifluoromethoxy functional group has received increasing attention in recent years due to its distinctive properties such as good metabolic stability,appropriate lipophilicity and special el...
关键词:Fluorine chemistry Trifluoromethoxylation NUCLEOPHILIC RADICAL Synthetic applications Methodology and Reactions 
Nucleophilic Radicals as Hydrogen Atom Abstractors in C(sp3)-H Functionalization Reactions被引量:1
《Chinese Journal of Chemistry》2023年第5期544-547,共4页Tao Li Jian Li Haohua Huo 
We are grateful for financial support from the National Key R&D Program of China(2021YFA1502500);National Natural Science Foundation of China(22071203);Fundamental Research Funds for the Central Universities(20720210014).
Hydrogen atom transfer(HAT)is an elementary mechanistic step in organic synthesis.The photoredox-catalyzed HAT has transformed organic synthesis by enabling the activation and subsequent cross-coupling of traditionall...
关键词:RADICALS Hydrogen atom transfer(HAT) C(sp^(3))-H functionalization Polarity matching Photocatalysis 
Metal-free nucleophilic 7,8-dearomatization of quinolines:Spiroannulation of aminoquinoline protected amino acids
《Chinese Chemical Letters》2023年第2期219-223,共5页Zhiguo Zhang Xiyang Cao Xiaoqing Song Gang Wang Bingbing Shi Xiang Li Nana Ma Lantao Liu Guisheng Zhang 
the National Natural Science Foundation of China (Nos. 22101074, 21877206, and 21772032);the 111 Project (No. D17007);Excellent Youth Foundation of Henan Scientific Committee (No. 222300420012);China Postdoctoral Science Foundation (No. 2019M660173);the Natural Science Foundation of Henan Province (No. 202300410233)。
Atom-and step-economy in IBX assisted diversity-oriented synthesis is achieved with a versatile AQ auxiliary α-amino acid analogs offering rapid access to polycyclic spiro-quinolines featuring a quaternary stereocent...
关键词:DEAROMATIZATION Spiroannulation Aminoquinoline Amino acids Hypervalent iodine reagents 
Boosting the cycling stability of rechargeable magnesium batteries by regulating the compatibility between nanostructural metal sulfide cathodes and non-nucleophilic electrolytes被引量:1
《Nano Research》2023年第2期2399-2408,共10页Xiaolan Xue Xinmei Song Anyang Tao Wen Yan Xiao Li Zhang Zuoxiu Tie Zhong Jin 
the National Key R&D Program of China(No.2017YFA0208200);the National Natural Science Foundation of China(Nos.22022505 and 21872069);the Fundamental Research Funds for the Central Universities(Nos.020514380266,020514380272,and 020514380274);the Scientific and Technological Innovation Special Fund for Carbon Peak and Carbon Neutrality of Jiangsu Province(BK20220008);the Nanjing International Collaboration Research Program(Nos.202201007 and 2022SX00000955);the 2021 Suzhou Gusu Leading Talents of Science and Technology Innovation and Entrepreneurship in Wujiang District(No.ZXL2021273).
Rechargeable magnesium batteries are attractive candidates for energy storage due to their high theoretical specific capacities,free of dendrite formation and natural abundance of magnesium.However,the development of ...
关键词:rechargeable magnesium batteries conversion reaction mechanism CuS nanoflower cathode non-nucleophilic electrolyte cycling lifespan 
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