supported by the National Natural Science Foun-dation of China(Nos.21690064,22001031);Key Laboratory of Bio-based Chemicals of Liaoning Province of China,the“111”project of the Ministry of Education of China and the Fundamental Research Funds for the Central Universities(No.DUT19RC(3)013).
Low-valence transition metallic complexes have drawn longstanding attention due to their high reactivity toward catalytic transformation of various small molecules.Among these known complexes,the low-valence metal cen...
supported by the National Natural Science Foundation of China(Nos.21690064,22001031);the key laboratory of Bio-based Chemicals of Liaoning Province of China;the“111”project of the Ministry of Education of China;the Fundamental Research Funds for the Central Universities(No.DUT19RC(3)013)。
Thiolate-bridged hetero-bimetallic complexes[Cp^(*)M(MeCN)N_(2)S_(2)FeCl][PF_(6)](2,M=Ru;3,M=Co,Cp^(*)=η^(5)-C_(5)Me_(5),N_(2)S_(2)=N,N'-dimethyl-3,6-diazanonane-1,8-dithiolate)were prepared by self-assembly of dimer...
National Natural Science Foundation of China (Nos. 21971092, 21901014, 21472072, 21871018, 21732001 and 21672017);Shenzhen Science and Technology Innovation Committee (No. JCYJ20200109141808025);Characteristic Innovation Project of Guangdong Provincial Education Department (No. 2020KTSCX295) for the financial support。
Pyridinium 1,4-zwitterionic thiolates were applied to a formal [3+2] annulation reaction with modified activated alkynes, affording various tetrasubstituted thiophenes with aryl, alkenyl, alkyl or silyl group at the s...
The electronic structure of the molecular ion has been calculated by DV-Xα method.The calculated nitrogen atomic charge is high in negative. The frontier molecular orbitals are mainly composed of Mo and S atomic vale...
The isomerization/chlorination of O, O-diallyl thiophosphoric (-nic) acid esters with phosphrus oxychloride gives S-allyl thiophosphoro (-no)chloride, which reacts with subsittuted phenol in chloroform in the presence...