THIOLATE

作品数：44被引量：14H指数：2
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Luminescence Regulation of Silver-Thiolate Clusters Protected by 1,2-Dithiolate-o-carborane
《Chinese Journal of Chemistry》2021年第1期81-86,共6页Li-Juan Liu Thomas C.W.Mak Shuang-Quan Zang 
This work was supported by the National Science Fund for Distinguished Young Scholars(No.21825106);the National Natural Science Foundation of China(No.21671175);the Program for Innovative Research Team(in Science and Technology)in Universities of Henan Province(No.19IRTSTHN022)and Zhengzhou University.
Engineering the surface of the metal clusters with the core structure maintained and tuning their luminescence in a wide range is still a challenge in the nanomaterial research.We modified six mono-pyridyl ligands wit...
关键词：Silver clusters Surface modification 1 2-Dithiolate-o-carborane LUMINESCENCE 
Electronic Structure of Thiolate-bridged Diiron Complexes and a Single-electron Oxidation Reaction＂ A Combination of Experimental and Computational Studies
《Chinese Journal of Chemistry》2016年第9期919-924,共6页Si Chen Lun Luo Yang Li Dawei Yang Jingping Qu Yi Luo 
This work was partly supported by the National Natural Science Foundation of China （Nos. 21429201, 21231003, 21571026）. The authors also thank the Network and Information Center of the Dalian University of Technology for part of the computational resources.
Single-electron oxidation of a diiron-sulfur complex [Cpπ＊Fe（μ-bdt）FeCp^＊] （1, Cp^＊=η^5-C5Me5; bdt = benzene-1,2-dithiolate） to [Cp^＊Fe（μ-bdt）FeCp^＊]]^＋ （2） has been experimentally conducted. The bdt...
关键词：density functional theory iron-sulfur cluster benzene-1 2-dithiolate non-innocent ligand single-electron oxidation 
Synthesis and Crystal Structure of a Decanuclear Silver(Ⅰ)-thiolate Compound Ag_(10)S[S_2P(OEt)_2]_8被引量：2
《Chinese Journal of Chemistry》2004年第7期673-677,共5页朱永宝 卢绍芳 黄小荥 黄子祥 吴锵金 
Project supported by the National Natural Science Foundation of China (Nos. 29673046 and 29733090); the Natural Science Foundation of Fujian Province (No. B96018) and the State Key Laboratory of Structural Chemistry.
A new decanuclear silver(I) compound Ag10(8-S)(dtp)8 [dtp=S2P(OEt)2] was isolated from a reaction mixture containing W2S4(dtp)2 and AgNO3, and its solid-state molecular structure was determinated by X-ray crystallogra...
关键词：silver(I)-thiolate complex diethyldithiophosphate ligand synthesis crystal structure 
[Co_3(1,2-S2C6H4)_3(PPh_3)_3]+, A basic triangle unit of some polynuclear molecules
《Chinese Journal of Chemistry》1994年第6期481-489,共9页JIANG, Fei-Long HUANG, Xiao-Ying HONG, Mao-Chun CAO, RongWU, Da-Xu, LIU , Han-QinState Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China 
Project supported by the National Natural Science Foundation of China.
[Co3(1,2-S2C6H4)3(PPh3)3][CoBr3(DMF)].sol (1, sol=CHCl3,O(C2H5)2,H2O) was obtained from the reaction of CoBr(PPh3)3 with Na2(S2C6H4) in chloroform. The Co3 core in the cation of 1 exhibits a metal-metal bonded isosce...
关键词：POLYNUCLEAR cobalt THIOLATE PHOSPHINE structure. 
Syntheses, properties and structures of copper and nickel complexes of 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate
《Chinese Journal of Chemistry》1994年第3期248-257,共10页YAO, Tian-Ming YOU, Xiao-ZengCoordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210008, ChinaYANG, Qing-ChuanChemistry Department, Beijing University, Beijing 100871, China 
Project supported by grants for key research project in climbing program from the State Science and Technology Commission,and the National Nature Science Foundation of China.
The reaction of CuCl2-2H2O or NiCl2.6H2O with K2(C5H6S4) [potassium salt of 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate] under nitrogen atmosphere resulted in the isolation of [Cu(C5H6S4)2]- or [Ni(C5H6S4)2]- as the t...
关键词：Dithiolene complex COPPER NICKEL single crystal. 
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