supported by the National Natural Science Foundation of China (No. 21771071, 22171094, and 21925104);the Key Scientific Research Projects of Universities in Henan Province (No. 21A150060)
Silver thiolate polymers are intercepted to form different structural fragments when reacting with variant solubilizing reagents,which usually serve as the starting point for the preparation of clusters.However,such a...
Supported by the National Natural Science Foundation of China(No.21301035)
A new one-dimensional polymer, [Zn(SC6H4S)(1,3-DPA)]n (1, SC6H4S = 1,4-ben- zenedithiolate and 1,3-DPA = 1,3-diaminepropane), has been synthesized and characterized by elemental analysis, PXRD, IR spectra, and s...
A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp*Fe(kt-SMe)N3]2 (Cp^* = η^5-C5Me5), was synthesized from [Cp*Fe(η-SMe)MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone ...
supported by the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192,20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
A new tri-nuclear mixed metal thiolate complex [Ag(PPh3)2]2[Ni(edtO2)2] 1 has been synthesized and structurally characterized by single-crystal diffraction.The molecule has a crystallographic inversion centre occu...
supported by the National Natural Science Foundation of China (20771003)
The title complex [RuH(CO)(PPh3)2(4-ClPhNHCS2)]·C6H14 has been prepared and characterized by X-ray diffraction analysis.It crystallizes in the triclinic system,space group P1 with a = 11.0817(2),b = 14.3889(...
Supported by the National Natural Science Foundation of China (No. 20371002);the Natural Science Foundation of Education Commission of Anhui Province (No. kj2007b092, kj2008b004)
A novel ion-pair palladium(Ⅱ) compound, (NOzBzPy)2[Pd(dmit)2] (NO2BzPy^+ = 1-(4-nitrobenzyl)pyridinium, dmit^2- = 2-thioxo-1,3-dithiole-4,5-bis(thiolate)), was synthesized and characterized by single-cry...
This work was supported by the National Natural Science Foundation of China (No. 20572014)
(C5H4SiMe2^tBu)2Ln^nBu reacted with 1 equiv, of elemental sulfur in toluene at ambient temperature to yield the corresponding lanthanocene thiolates [(C5H4SiMe2^tBu)2Ln(μ-S^nBu)]2 (Ln = Y (1), Er (2)). Co...
The project was supported by the National Natural Science Foundation of China (No. 20525101), the NSF of Jiangsu Province (No. BK2004205), State Key Laboratory of Structural Chemistry (No. 030066) and Key Laboratory of Organic Synthesis of Jiangsu Province (No. JSK001)
Reaction of CuBr2 with TabHPF6/Et3N in methanol followed by dissolving the resulting precipitate in hydrobromic acid yielded purple blocks of the title complex [Tab-Tab][CuBr4] 1 (C18H26CuBraN2S2). 1 crystallizes in...
A di-molybdenum carbonyl compound containing thiolate and dithiocarbamate ligands, [Bu4N][(CO)4Mo(μ-SC6H5)2Mo(C5H10dtc)(CO)2] 1 (CsH10dtc = S2CNC5H10), has been prepared by reaction of [Mo2(SC6H5)2(CO)8...
This research was supported by the State Key Laboratory of Structural Chemistry, the National Natural Science Foundation of China (20273073, 20333070, 90206040) and Natural Science Foundation of Fujian Province (2004J041, 2003J042, 2004HZ01-1)
A 1-D zigzag chain [Sn(edt)2(p-phenylenediamine)], (edt=ethane-l,2-thiolate) was synthesized by self-assembly and determined by X-ray structure analysis. The title compound (C10H16N2S4Sn) crystallizes in monoc...