supported by National Basic Research Program of China (2014CB931804);the National Natural Science Foundation of China (21302061 and 21531003)
High density of phenyl rings makes PAF-1 have robust structure and highly lipophilic pore, which make it very suitable for organocatalysis. However, there is no report about using PAF-1 as platform for enantioselectiv...
Supported by the National Natural Science Foundation of China(No.21174052) and the Natural Science Foundation of Jilin Province of China(Nos.20160101311JC, 20170101105JC).
Chiral organoeatalysts of 4-adamantane amide based on L-proline with double hydrogen potential were synthesized and used in asymmetric aldol reactions. The reactions were evaluated in toluene under -20℃. A series of ...
Prolinamido-glycoside catalyzed asymmetric aldol reaction in aqueous media is reported. The reactions are rapid and highly stereoselective when water is used as solvent. The stereoselectivities were under influence of...
An approach based on combinations of various water compatible Lewis acids and lipophilic group containing amphiphilic prolinamide co-catalysts has been evaluated for the direct asymmetric Aldol reaction. From the broa...
the National Natural Science Foundation of China (20772056);Jiangsu 333 Program (for Pan) for the generous financial support;The research funds for Pan from the Qing-Lan Program of Jiangsu Province;the Kua-Shi-Ji Program of the Education Ministry of China
An efficient direct asymmetric aldol reaction with zinc triflate and prolinamides as combined catalysts is reported.A series of chiral prolinamides have been designed and used in the direct aldol reaction resulting in...
Project supported by the National Natural Science Foundation of China (Nos. 20342007, 20462003, 20452001 and 20421202).
An environment-friendly L-prolinamide catalyzed aldol reaction has been developed. The reaction exhibited broad substrate generality, and high yields with good diastereoselectivity were obtained for cyclic ketones.The...