SYNTHONS

作品数:17被引量:10H指数:2
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相关领域:理学更多>>
相关期刊:《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Structural Chemistry》《Green Synthesis and Catalysis》更多>>
相关基金:国家自然科学基金湖北省自然科学基金安徽省自然科学基金更多>>
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Bimolecular reduction of carbon dioxide: double synthons for alkynes trifunctionalization
《Science China Chemistry》2024年第3期841-847,共7页Wenfang Xiong Xiaobin Tan Hongjian Liu Baiyao Zhu Jinwu Zhao Jianxiao Li Chaorong Qi Huanfeng Jiang 
supported by the National Natural Science Foundation of China(21971073,22001075,22231002);the Natural Science Foundation of Guangdong Province(2019A1515011468);the Discipline Construction Project of Guangdong Medical University(4SG23231G,4SG23249G);the Ordinary University Characteristic Innovation Project of Guangdong Province(2022KTSCX047);the Key-Area Research and Development Program of Guangdong Province(2020B010188001)。
Carbon dioxide reduction, as a sustainable and versatile strategy for the access of chemical fuels, has attracted increasing attention and enormous efforts have been devoted to it in recent years. However, employing c...
关键词:carbon dioxide bimolecular reduction trifunctionalization double synthons 
Recent advances of versatile reagents as controllable building blocks in organic synthesis
《Chinese Chemical Letters》2024年第2期24-43,共20页Shaomin Chen Luigi Vaccaro Yanlong Gu 
supported by the National Natural Science Foundation of China(No.22072049);National Key Research and Development Project(No.2022YFE0124100);Major Special Projects of Science and Technology of Ordos(No.2022EEDSKJZDZX003);Program for HUST Academic Frontier Youth Team(No.2019QYTD06)is also acknowledged;Chen is also grateful for the financial support from China Scholarship Council(CSC).
Diversity-oriented synthesis is a powerful and interesting synthetic tool for the rapid construction of structurally complex and privileged scaffolds from readily accessible starting materials.To date,diversity-orient...
关键词:Versatile reagents Divergent synthesis Dual synthons Bond cleavage Tandem reactions 
Diastereodivergent formal[4+1]cycloaddition of azoalkenes as one-carbon synthons
《Green Synthesis and Catalysis》2023年第3期258-262,共5页Chun-Yan Guan Tian-Jiao Han Shi-Kun Jia Yuan-Zhao Hua Guang-Jian Mei 
support from the Natural Science Foundation of Henan Province(No.222300420084);the Application Research Plan of Key Scientific Research Projects in Colleges and Universities of Henan Province(No.22A150056)is gratefully acknowledged.
The first diastereodivergent formal[4+1]cycloaddition reactions of azoalkenes with p-quinone methides(pQMs)have been accomplished.The reported reaction occurred via a domino oxa-1,4-addition/1,6-addition process,allow...
关键词:Azoalkene One-carbon synthon Diastereodivergent [4+1]Cycloaddition para-Quinone methides 
Metal-free synthesis of 3-trifluoromethyl-1,2,4-triazoles via oxidative cyclization of trifluoroacetimidohydrazides with N,N-dimethylformamide as carbon synthons
《Green Synthesis and Catalysis》2022年第4期385-388,共4页Shu-Ning Lu Jiajun Zhang Jingxian Li Zhengkai Chen Xiao Feng Wu 
We thank the financial support from the Natural Science Foundation of Zhejiang Province(No.LY19B020016);the K.C.Wong Education Foundation(No.GJTD-2020-08).
A metal-free approach for the synthesis of 3-trifluoromethyl-1,2,4-triazoles via I2-mediated oxidative cyclization of readily accessible trifluoroacetimidohydrazides with N,N-dimethylformamide(DMF)has been disclosed.I...
关键词:METAL-FREE Oxidative cyclization 3-Trifluoromethyl-1 2 4-triazole Trifluoroacetimidohydrazides N N-DIMETHYLFORMAMIDE Trifluoromethyl-substituted N-Heterocycles 
Achieving a stable COF with the combination of“flat”and“twist”large-size rigid synthons for selective gas adsorption and separation被引量:1
《Chinese Chemical Letters》2022年第6期3017-3020,共4页Jingyang Li Ying He Yongcun Zou Yan Yan Zhiguang Song Xiaodong Shi 
A new type of covalent organic framework(COF)was achieved using combination of structrally rigid and conformationally othorganal building blocks.The N-2-aryl-substituted triazole derivative(NAT-CHO)was prepared with c...
关键词:N-2-Aryl triazole ETTA Covalent organic framework Gas adsorption and separation 
Phosphafluorenyl lithiums:direct synthesis from white phosphorus,structure and diversified synthons被引量:2
《Science China Chemistry》2022年第2期322-327,共6页Jingyuan Hu Zhengqi Chai Wei Liu Zhe Huang Junnian Wei Wen-Xiong Zhang 
supported by the National Natural Science Foundation of China(22131001,21725201,21890721);the High-performance Computing Platform of Peking University。
While rich chemistry of phospholyl anions is discovered,phosphafluorenyl anions are only proposed as the critical intermediates for the synthesis of phosphafluorenes.In this article,we reported the direct synthesis of...
关键词:white phosphorus organophosphorus compounds P–C bond formation P_(4)functionalization phosphafluorenyl lithium 
Syntheses, Crystal Structures and Hydrogen-bonding Motif of Two Glycoluril Derivatives被引量:1
《Chinese Journal of Structural Chemistry》2019年第5期754-760,669,共8页LIU Xue-Mei WANG Dong-Hua SONG Xin-Jian WANG Jun-Gang 
supported by the Natural Science Foundation of Hubei Province(No.2017CFB355);the State Undergraduate Innovative Training Program(No.201610517012)
The synthesis and aggregation behavior of two glycoluril derivatives were descrybed.The crystal of compound 1 belongs to the triclinic system,space group ■,with a=8.946(1),b=13.445(2),c=20.361(3)?,α=89.517(3...
关键词:hydrogen bond GLYCOLURIL supramolecuclar SYNTHONS crystal engineering 
Three New Coordination Polymers Constructed by Adjusting the Angles of Pyridyl or Imidazolyl-based Synthons: Structures and Solid UV-vis Properties
《Chinese Journal of Structural Chemistry》2016年第8期1245-1252,共8页周春辉 周杰 胡振原 金矿 胡劲松 
supported by the Natural Science Foundation of China(21301005);Natural Science Foundation of Anhui Province(1408085QB31)
Three new 2D metal-organic frameworks, [M(BIDPE)2(bdc)2]n(M = Co for 1, Ni for 2) and [Ni(PIDPE)2(H2O)2(bdc)]n(3)(BIDPE = 4,4A-bis(imidazol-1-yl) diphenyl ether, PIDPE =4-(pyridyl)-4A-(imidazol-1-y...
关键词:metal-organic frameworks intermolecular hydrogen bonds solid UV-vis spectrum 
Multi-component Hydrogen-bonding Organic Salts Formed from 1-Methylpiperazine with Aromatic Carboxylic Acids: Synthons Cooperation and Crystal Structures
《Chemical Research in Chinese Universities》2015年第1期9-15,共7页YANG Yu XU Wenyan HU Yanjing WANG Lei HUANG Keke 
Supported by the National Natural Science Foundation of China(Nos.51372125, 21203106), the Fund of the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, China(No.2013-34), and the Scientific and Technical Development Project of Qingdao City, China(No. 13-1-4-184-jch).
1-Methylpiperazine was employed to crystallize with 2,4-dihydroxybenzoic acid and 1,8-naphthalene acid, affording two multi-component hydrogen-bonding salts [(C5H14N2)^2+-(C7H5O4)2^·H2O](1) and [(C5H14N2)^2...
关键词:Structure characterization Hydrogen bond SYNTHON Organic salt 
Construction of interesting organic supramolecular structures with synthons cooperation in the cocrystals of 1H-benzotriazole and hydroxybenzoic acids被引量:2
《Science China Chemistry》2012年第12期2515-2522,共8页WANG Lei ZHAO Lei XUE RuiYu LU XiFeng WEN YongHong YANG Yu 
supported by the National Natural Science Foundation of China (20701023 and 20971076);the Natural Science Foundation of Shandong Province,China (BS2010CL013 and2009ZRB019KH)
Multifunctional molecules are capable of assembling via different supramolecular synthons, or hydrogen bond motifs, between the same or different functional groups, leading to the possibility of cocrystal. Utilization...
关键词:CO-CRYSTALS crystal structure supramolecular synthons 1H-benzotriazole 
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