PHOSPHINIDENE

作品数:2被引量:0H指数:0
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相关领域:理学更多>>
相关期刊:《Chinese Journal of Chemistry》《CCS Chemistry》更多>>
相关基金:天津市自然科学基金王宽诚敎育基金国家自然科学基金更多>>
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Hydrogenation of Alkenes Catalyzed by Rare-Earth Metal Phosphinophosphinidene Complexes:1,2-Addition/Elimination Versusσ-Bond Metathesis Mechanism
《CCS Chemistry》2022年第10期3309-3318,共10页Bin Feng Hao-Yu Zhang Hongling Qin Qian Peng Xuebing Leng Yaofeng Chen 
supported by the National Natural Science Foundation of China(nos.21732007,21890721,21821002,21890722,and 21950410519);the Natural Science Foundation of Tianjin Municipality(nos.19JCJQJC62300 and 18JCYBJC21400);the Tianjin Research Innovation Project for Postgraduate Students(no.2019YJSB081);the Frontiers Science Center for New Organic Matter[Nankai University(no.63181206)];the K.C.Wong Education Foundation,and the Shanghai Municipal Committee of Science and Technology.
Rare-earth metal complexes have been used as catalysts for many types of reactions.However,the mechanistic studies showed that basically,these various reactions proceeded withσ-bond metathesis of RE–E bond(RE:rare-e...
关键词:rare-earthmetal PHOSPHINIDENE ALKENE HYDROGENATION reaction mechanism density functional theory calculations 
Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex
《Chinese Journal of Chemistry》2014年第8期752-756,共5页Wei Wang Yingdong Lv Xiaofeng Gou Xuebing Leng Yaofeng Chen 
the National Natural Science Foundation of China(Nos.21325210,21132002 and 21121062);the State Key Basic Research&Development Program(No.2012CB821600).
Reactions of bis-scandium bridged phosphinidene complex,[LSc(μ-PAr)]_(2)(L=MeC(NDIPP)CHC(Me)(NCH_(2)CH_(2)N(^(i)Pr)_(2)),DIPP=2,6-(^(i)Pr)_(2)C_(6)H_(3);Ar=2,6-Me_(2)C_(6)H_(3))(1),with pinacolborane,catecholborane,a...
关键词:catecholborane PHOSPHINIDENE pinacolborane SCANDIUM REACTIVITY 
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