OLEFIN

作品数：174被引量：298H指数：9
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Enhanced Efficiency of Amide-Substituted Quinuclidine-Boranes as Hydridic Hydrogen Atom Transfer Catalysts for Photoinduced Hydroalkylation of Unactivated Olefins
《Chinese Journal of Chemistry》2024年第24期3227-3233,共7页Xiao Yang Mengdi Ma Meichen Xu Yubing Pang Haiying Zhao Juntao Ye 
the National Natural Science Foundation of China(grant nos.22371180 and 22001163 to Y.J.and 22361032 to H.Z.);Shanghai Jiao Tong University(SJTU)is acknowledged.Dr.Pandaram Sakthivel(SJTU)is acknowledged for reproducing the results of compounds 6,10,and 21.
An amide-substituted quinuclidine-borane has been identified as a more efficient hydridic hydrogen atom transfer(HAT)catalyst for the hydroalkylation of unactivated olefins under visible-light irradiation.^(1)H NMR ti...
关键词：Hydrogen atom transfer BORANE Unactivated olefin HYDROALKYLATION Photocatalysis 
Halogen Bond Catalysis on Carbonyl-Olefin Ring-Closing Metathesis Reaction:Comparison with Lewis Acid Catalysis
《Chinese Journal of Chemistry》2022年第11期1275-1284,共10页Ying Li Yuanyuan Sun Lingpeng Meng Qingzhong Li Yanli Zeng 
This work was supported by the Natural Science Foundation of Hebei Province(B2019205113,B2019205061);the National Natural Science Foundation of China(21973025);the Science Foundation of Hebei Normal University(L2020Z04).
The carbonyl-olefin ring-closing metathesis reactions have become a powerful tool for carbon-carbon bond formation.In this work,the halogen bond catalysis and classical Lewis acid catalysis on the carbonyl-olefin ring...
关键词：Halogen bond donors Lewis acids Electrostatic interactions Orbital interaction Carbonyl-olefin ring-closing metathesis 
Solvent-Controlled Construction of Molecular Chains and Bowls/Sieves from a Bent Dipyridyl Ligand被引量：1
《Chinese Journal of Chemistry》2021年第9期2523-2528,共6页Xiao-Yun Tian Xiao-Xian Chen Chao Wang Zi-Ming Ye Dong-Dong Zhou Jie-Peng Zhang 
supported by the NSFC(Nos.21731007,21821003,22090061,and 22071272);the Guangdong Pearl River Talents Program(No.2017BT01C161);the Guangzhou Science and Technology Bureau(No.202102020296).
Solvothermal reactions of 3,6-di(pyridin-4-yl)-9H-carbazole(dpc)with Cu(ll)yielded crystals of two new coordination complexes,namely[Cu(CH_(3)COO)_(2)(dpc)(H_(2)O)_(2)]n-xGuest(1)and[Cu_(13)(HCOO)_(16)(dpc)16(H_(2)O)6...
关键词：Self-assembly Crystal engineering Microporous materials Molecular sieve Olefin drying 
Asymmetric Cationic [P, O] Type Palladium Complexes in Olefin Homopolymerization and Copolymerization
《Chinese Journal of Chemistry》2017年第8期1209-1221,共13页Shuoyan Xiong Lihua Guo Shumiao Zhang Zhe Liu 
Acknowledgement This work was supported by the National Natural Science Foundation of China （NSFC, No. 21304054）, the Taishan Scholar Foundation, Foundation of Qufu Normal University （No. xkJ201603）, and the National College Students Innovation Project （No. 201610446029）.
Metal-catalyzed ethylene homopolymerization and ethylene-polar monomer copolymerization to produce new kinds of polyolefins with novel microstructures are of great interest. So far, there are some disadvantages for tr...
关键词：PALLADIUM olefin polymerization COPOLYMERIZATION cationic metal center substituent effect 
Asymmetric Hydroformylation of Olefins Catalyzed by a Chiral Diphosphite-Rhodium Complex被引量：1
《Chinese Journal of Chemistry》2004年第2期203-206,共4页鄢明 黎星术 陈新滋 
Project supported by the Suzhou University and the Hong Kong Polytechnic University ASD Fund and University Grants Committee Area of Excel-lence Scheme in Hong Kong (AoE P/10-01).
A C2-symmetrical aryl diphosphite derived from chiral binaphthol was prepared and its rhodium complex was used as catalysts in the asymmetric hydroformylation of olefins. High catalytic activity and good regioselectiv...
关键词：diphosphite chiral ligand asymmetric hydroformylation OLEFIN rhodium complex 
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