support from the National Natural Science Foundation of China(Nos.21971104,22001114 and 22271136);Shenzhen Science,Technology and Innovation Commission(JCYJ20220814203252001);Shenzhen Key Laboratory of Small Molecule Drug Discovery and Synthesis(ZDSYS20190902093215877);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);Guangdong Innovative Program(No.2019BT02Y335);Education Department of Guangdong Province,Key Research Projects in Colleges and Universities in Guangdong Province(2021ZDZX2035);Shenzhen Nobel Prize Scientists Laboratory Project(C17783101),Innovative Team of Universities in Guangdong Province(2020KCXTD016);Guangdong Natural Science Foundation(2022A1515010456)is greatly appreciated.
As one of the most common structural motifs in natural products,cyclopentenones usually can be fabricated by Nazarov cyclization using divinyl ketones or functionalized tertiary divinyl carbinols(TDCs)as substrates.Ho...
This work was supported by the National Natural Science Foundation of China(Nos.21725201,21890721 and 22131001)。
As an important part of pericyclic reaction,6π 1,5-electrocyclization plays an important role in organic synthesis and chemical theory.Many types of five-membered rings could be constructed via 1,5-electrocyclization...
The recent development of microwave-assisted aqueous synthesis of polyheterocyclic-fused quinoline-2-thiones through 6π-electrocyclization was highlighted.