PARACYCLOPHANE

作品数：9被引量：6H指数：1
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相关领域：理学更多>>
相关作者：史真更多>>
相关机构：西北大学更多>>
相关期刊：《Chinese Journal of Polymer Science》《有机化学》《西北大学学报（自然科学版）》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金中国博士后科学基金更多>>
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Synthesis of Planar-Chiral[2.2]Paracyclophane-Based Oxazole-Pyrimidine Ligands and Application in Nickel-Catalyzed 1,2-Reduction ofα,β-Unsaturated Ketones
《Chinese Journal of Chemistry》2024年第7期705-710,共6页Juan Wang Qing-Xian Xie Xiang Li Chang-Bin Yu Yong-Gui Zhou 
Financial support from National Natural Science Foundation of China (22171260);K.C.Wong Education Foundation of CAS (GJTD-2020-08)is acknowledged.
The planar-chiral ligands have been widely applied as a class of unique and significant ligands in asymmetric catalysis.Among them,chiral[2.2]paracycyclophane has emerged as a privileged type of planar-chiral framewor...
关键词：Oxazole-pyrimidine ligands Planar chirality Nickel HYDROBORATION Asymmetric synthesis 
Remarkably Improved Gas Separation Performance of Polyimides by Forming“Bent and Battered”Main Chain Using Paracyclophane as Building Block被引量：1
《Chinese Journal of Polymer Science》2023年第10期1617-1628,共12页Lu-Jun Huang Ya-Tao Weng Aqib Raiz Zhi-Jie Mao Xiao-Hua Ma 
financially supported by the National Natural Science Foundation of China (Nos. 22078245 and 21861016);YLU-DNL Fund (No. 2022009)
The design and development of highly permeable,selective and stable polymer membranes are great challenges in the gas separation industry.Herein,we constructed two intrinsic microporous polyimides(6FPCA and 6FMCA)deri...
关键词：Polyimide of intrinsic microporosity 2 2'-Paracyclophane Molecular intrinsic microporosity Gas separation Permeability/selectivity trade-off 
Planar Chiral[2.2]Paracyclophane-Based Zr(IV)Metal-Organic Frameworks被引量：1
《CCS Chemistry》2023年第7期1635-1643,共9页Hong Jiang Wenqiang Zhang Bang Hou Yan Liu Yong Cui 
This work was financially supported by the National Natural Science Foundation of China(grant nos.21620102001,91856204,91956124,and 21875136);Key Project of Basic Research of Shanghai(grant no.19JC1412600);Shanghai Rising-Star Program(grant no.19QA1404300),and the China Postdoctoral Science Foundation(grant no.2020M681280).
Self-assembly has been widely explored to improve the circularly polarized_(lum)inescence(CPL)activities of molecular chromophores,but it is hard to amplify CPL while maintaining strong emissions.Optically pure,planar...
关键词：metal-organic frameworks circularly polarized luminescence planar chirality quantumyield dissymmetric factor 
Adsorption of polyhaloalkane vapors by adaptive macrocycle crystals of Wreath Arene through C-halogen…π interactions被引量：1
《Chinese Chemical Letters》2022年第4期1970-1974,共5页Shu Niu Liang-Liang Mao Hongyan Xiao Yongye Zhao Chen-Ho Tung Li-Zhu Wu Huan Cong 
Financial support from the National Natural Science Foundation of China (Nos. 21672227, 21922113, 21988102, 22071257);Chinese Academy of Sciences (Nos. XDB17000000);the National Key Research and Development Program (No. 2017YFA0206903);K. C.Wong Education Foundation;the TIPC Director’s Fund。
Polyhaloalkanes are broadly useful yet environmentally harmful stock chemicals,therefore the development of adsorbent materials with capacity and selectivity for polyhaloalkane vapors is highly desirable.Here we repor...
关键词：MACROCYCLE PARACYCLOPHANE Halogen…π Polyhaloalkane ADSORPTION 
Metal-free catalytic enantioselective silylation of aromatic aldehydes in water被引量：1
《Chinese Chemical Letters》2018年第9期1359-1362,共4页Yuwen Huo Panpan Shen Wenzeng Duan Zhen Chen Chun Song Yudao Ma 
Financial support from the National Natural Science Foundation of China(Nos.21372144,81473085);Department of Science and Technology of Shandong Province
An environmentally friendly and transition metal-free method for the preparation of chiral α- hydroxysilanes was developed. Enantioselective addition of a silicon nucleophile to aromatic aldehydes in water was achiev...
关键词：SILYLATION Asymmetric catalysis N-Heterocyclic carbene [2.2]Paracyclophane α-Hydroxysilane 
Synthesis of Novel N-Ferrocenesulfonyl Paracyclophane
《有机化学》2003年第z1期293-293,共1页YANG Bing-Qin ZHU Ai-Lin SUN Jing 
Project supported by the National Natural Science Foundation of China (No. 2017204) and the Natural Science Foundation of Shaanxi Province (No. FF01202).
　　There exists a close relationship between the field of synthetic host-guest chemistry and molecular recognition in biological systems. Artificial host-guest systems have been designed to mimic the binding of subst...
MODELS FOR π-π INTERACRIONS IN “MOLECULAR METALS” IONIZATION ENERGIES, ELECTRONIC STRUCTURE AND THROVGH-SPACE/THROUGH-BOND INTERACTIONS IN [2,2] PARACYCLOPHANE
《Chinese Chemical Letters》1994年第3期221-224,共4页Han Xing LIU (Anvanced Materials Research Institute, Wuhan University of Technology, Wuban, 430070)Chia Chung SUN(Institute of Theoretical Chemistry, Jilin University, Cbangchun, 130021) 
The through-space and through-bond interactions of molecular orbitals in [2,2] paracyclophane are studied by the approved MS-X. method with overlapping atomic-sphere. The calculation results show the through-space in...
关键词：SPACE INTERACTIONS ELECTRONIC ENERGIES FOR AND INTERACroNS IONIZATION MODELS PARACYCLOPHANE 
PEARL-NECKLACE-POLYMER: COPOLYMERIZATION OF C_(60) WITH PARACYCLOPHANE
《Chinese Chemical Letters》1994年第2期149-152,共4页Shao Ming HUANG Xue Hai YU Chang Zheng YANG and Li Fen WU (Chemistry Department,Nanjing University,Nanjing,210008) 
Copolymerization of C60 with paracyclopbane at high temperature was.atudied. The copolymer was cbaracterizod by IR, ESR, UV- VIS and DSC and its.tructures and mechanism were proposed.
[2.2]Paracyclophane的合成被引量：2
《西北大学学报（自然科学版）》1990年第2期49-52,共4页史真 
本文采用二卤代烃与硫醇在碱的存在下偶合的方法制备二硫杂Cyclophane化合物,然后经光化脱硫得到相应的[2.2]Paracyclophane.两步的产率均较高,且操作简便,适用于各类Cyclophane化合物的合成。
关键词：环吩 合成 二卤代烃 硫醇 偶合 
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