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作品数：12被引量：10H指数：2
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相关领域：理学医药卫生更多>>
相关作者：陈磊更多>>
相关机构：中国科学院河北大学更多>>
相关期刊：《Chinese Journal of Structural Chemistry》《合成化学》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金：国家自然科学基金中国博士后科学基金上海市自然科学基金上海市青年科技启明星计划更多>>
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Carbene-catalyzed activation of cyclopropylcarbaldehydes for mannich reaction andδ-lactam formation:remote enantioselecitvity control and dynamic kinetic asymmetric transformation被引量：1
《Science China Chemistry》2021年第6期985-990,共6页Jie Lv Jun Xu Xuling Pan Zhichao Jin Yonggui Robin Chi 
This work was supported by the National Natural Science Foundation of China(21772029,21801051,21961006,22071036,82360589,81360589);The 10 Talent Plan(Shicengci)of Guizhou Province([2016]5649);the Guizhou Province Returned Oversea Student Science and Technology Activity Program[(2014)-2];the Science and Technology Department of Guizhou Province([2018]2802,[2019]1020);the Program of Introducing Talents of Discipline to Universities of China(111 Program,D20023);at Guizhou University,Frontiers Science Center for Asymmetric Synthesis and Medicinal Molecules,Department of Education,Guizhou Province[Qianjiaohe KY(2020)004];the Guizhou Province First-Class Disciplines Project[(Yiliu Xueke Jianshe Xiangmu)-GNYL(2017)008];Guizhou University of Traditional Chinese Medicine(China),and Guizhou University.
An N-heterocyclic carbene(NHC)-catalyzed enantioselective Mannich reaction of the remoteγ-carbon of cyclopropylcarbaldehydes is disclosed for the first time.Diastereo-and enantiomerically enriched multicyclicδ-lacta...
关键词：N-heterocyclic carbene ORGANOCATALYSIS dynamic kinetic asymmetric transformation 1-cyclopropylcarbaldehydes asymmetric reactions 
Michael addition reactions of cyclanones with acrylamides:Producing 2-carbamoylethyl derivatives or ene-lactams
《Science China Chemistry》2008年第11期1044-1050,共7页DAI WeiFeng WANG ChaoHua ZHANG Xi ZHANG JinMing LANG MeiDong 
the National Natural Science Foundation of China (Grant Nos. 20374013 and 20674019);Program for New Century Excellent Talents in University (Grant No. NCET-04-0413);Science and Technology Commission of Shanghai Municipality (Grant Nos. 03JC14023 and 05DJ14005);"Shu Guang" Project of Shanghai Municipal Education Commission and Specialized Research Fund for the Doctoral Program of Higher Education (Grant No.20060251015)
The electron-withdrawing groups (EWGs) in the electrophilic alkenes employed in the Michael addition reaction are almost only CO2R, CN, COR, NO2, and SO2Ph. Although amides (CONR1R2) are also typical electron-withdraw...
关键词：MICHAEL addition reaction cyclanone ACRYLAMIDE ene-lactam 2-carbamoylethyl derivative 
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