TRANSMETALATION

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相关期刊：《Chinese Journal of Chemistry》《Journal of Rare Earths》《Open Journal of Physical Chemistry》《Science China Chemistry》更多>>
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Access to Versatile Functionalized Cu(Ⅲ) Complexes Enabled by Direct Transmetalation to Well-Defined Copper(Ⅲ) Fluoride Complex Me_(4)N^(+)[Cu(CF_(3))_(3)F]^(-)
《Chinese Journal of Chemistry》2024年第10期1107-1113,共7页Guangyu Wang Huaiyuan Li Xuebing Leng Long Lu Qilong Shen 
the financial support from the National Key Research and Development Program of China(No.2021YFF0701700);the National Natural Science Foundation of China(22061160465).
The invention of a well-defined Cu(Ⅲ)fluoride complex Me_(4)N^(+)[Cu(CF_(3))_(3)(F)]^(-)1 enabled to access a versatile of functionalized Cu(Ⅲ)complexes[Me_(4)N]^(+)[Cu(X)(CF_(3))_(3)]^(-)(X=C_(6)F_(5),C_(6)F_(5)C≡...
关键词：FLUORINE COPPER Cu(Ⅲ) Cu(Ⅲ)fluoride TRIFLUOROMETHYL 
Rhodium-catalyzed enantio-and diastereoselective carboamidation of bicyclic olefins toward construction of remote chiral centers and axis
《Science China Chemistry》2023年第7期2046-2052,共7页Jinlei Wang Xingwei Li 
supported by the National Natural Science Foundation of China(21525208);the Fundamental Research Funds for the Central Universities(2020CSLZ005,GK202103031)
The precise control of multiple chiral elements through a single step catalytic process remains a significant challenge in asymmetric catalysis.Reported herein is rhodium-catalyzed three-component asymmetric carboamid...
关键词：carboamidation axial chirality DESYMMETRIZATION bicyclic olefin TRANSMETALATION 
Theoretical Investigation of the Mechanism of Rh(III)-catalyzed Annulation of 2-Biphenylboronic Acid with Activated Alkene
《Chemical Research in Chinese Universities》2023年第2期276-282,共7页LU Nan MIAO Chengxia LAN Xiaozheng 
National Natural Science Foundation of China(Nos.21973056,21972079);Natural Science Foundation of Shandong Province,China(No.ZR2019MB050);Project of the Key Laboratory of Agricultural Film Application of Ministry of Agriculture and Rural Affairs,China.
The mechanism is investigated for Cp^(tBu)Rh(OH)_(2)-catalyzed annulation of 2-biphenylboronic acid with three activated alkenes using M06-2X functional.The reaction comprises transmetalation via two steps and followi...
关键词：ANNULATION Activated alkene TRANSMETALATION Coordination/insertion M06-2X functional 
The role of Cul in the siloxane-mediated Pd-catalyzed cross-coupling reactions of aryl iodides with aryl lithium reagents
《Chinese Chemical Letters》2021年第1期441-444,共4页Yu Chen Xiao Zhang Fang Liu Gucheng He Ju Zhang K.N.Houk Amos BSmith III Yong Liang 
financially supported by the National Natural Science Foundation of China(No.21803030);the Fundamental Research Funds for the Central Universities,the National Thousand Young Talents Program;the Jiangsu Innovation&Entrepreneurship Talents Plan;the NSF of Jiangsu Province(No.BK20170631)in China;the National Institutes of Health(No.CA-019033);the National Science Foundation in USA(No.CHE-1361104)。
Experiments indicate that a catalytic amount of Cul plays an important role in the siloxane-mediated Pd-catalyzed cross-coupling reactions with the direct use of organolithium reagents.Addition of organolithium to the...
关键词：CROSS-COUPLING CUI DFT calculation Reaction mechanism TRANSMETALATION 
Products and Kinetics of the Reaction of Monomeric Target Bis-(Acetylacetonato) Copper(II) with Transmetalator Bis-(Diethoxydithiophosphato) Zinc(II) in Methylene Chloride
《Open Journal of Physical Chemistry》2015年第2期39-48,共10页Hisham A. Abo-Eldahab 
Reaction of bis-(acetylacetonato) copper(ΙΙ) (A) with transmetalator Zn((EtO)2PS2)2 (B2;Et = ethyl) in methylene chloride is a simple irreversible second-order process over a wide temperature range which is the firs...
关键词：KINETICS Mechanism TRANSMETALATION Transmetallators Thermodynamics 
Synthesis of Lanthanide Cryptates by Transmetalation Reaction
《Journal of Rare Earths》2005年第S1期543-546,共4页胡学雷 刘焕 胡丹 袁军 陈中 黄齐茂 潘志权 
ProjectsupportedbytheNationalNaturalScienceFoundationofHubeiProvince(2005ABA021)andtheEducationOfficeofHubeiProvince(D200515004)
New lanthanide cryptates [LnL](ClO_4)_3 (Ln=Eu 3+, Ce 3+, Pr 3+, Sm 3+, Gd 3+, Tb 3+; L=1, 4, 12, 15, 18, 26, 31, 39, 42, 43, 44-undecaazapentacyclo-[13.13.13.1 6, 10.1 20, 24.1 33, 37]-tetratetraconta-4, 6, 8, 10(44)...
关键词：LANTHANIDE CRYPTATE transmetalation reaction synthesis rare earths 
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